AbstractIn this paper, a revised version of the particle growth model (PGM) describing olefin co-polymerization with metallocene catalysts is proposed. The model is used to calculate the reaction rate of hexane–propylene co-polymerization under different operating conditions. Results are compared with experimental data obtained by calorimetric technique in order to validate the model. Good agreement between calculated and experimental results is shown
A model-based approach was employed to reveal the elementary steps and the corresponding rate consta...
Coupled single-particle growth and kinetics modeling for styrene polymerization over silica-supporte...
The early stages (from less than 1s to few minutes) of catalytic olefin polymerization are still fai...
Two improved multigrain models (MGMs) for preparing homopolypropylene and long chain branched pol...
>A mathematical model, including the main morphological features of the polymerization process, is d...
In this paper, a mathematical model describing olefin polymerization with metallocene catalysts is p...
The disintegration of the catalyst particle during the polymerization of ethylene into successively ...
The olefins polymerization process in a slurry reactor is discussed. The reaction rate dynamics was ...
A two-dimensional (2D) single particle model for the copolymerization of propylene-ethylene with het...
A two-dimensional single particle finite element model was used to examine the effects of particle f...
A model for studying the catalyst fragmentation in the early stages of olefin polymerization is pres...
The behaviour of silica supported metallocene catalyst in the early moments of olefin polymerization...
Polymer particle growth in the early stages of olefin polymerization has been investigated using met...
A study was performed to improve the model for metallocene catalyzed polyolefin polymerization in fl...
Kinetics-based differences in the early stage fragmentation of two structurally analogous silica-sup...
A model-based approach was employed to reveal the elementary steps and the corresponding rate consta...
Coupled single-particle growth and kinetics modeling for styrene polymerization over silica-supporte...
The early stages (from less than 1s to few minutes) of catalytic olefin polymerization are still fai...
Two improved multigrain models (MGMs) for preparing homopolypropylene and long chain branched pol...
>A mathematical model, including the main morphological features of the polymerization process, is d...
In this paper, a mathematical model describing olefin polymerization with metallocene catalysts is p...
The disintegration of the catalyst particle during the polymerization of ethylene into successively ...
The olefins polymerization process in a slurry reactor is discussed. The reaction rate dynamics was ...
A two-dimensional (2D) single particle model for the copolymerization of propylene-ethylene with het...
A two-dimensional single particle finite element model was used to examine the effects of particle f...
A model for studying the catalyst fragmentation in the early stages of olefin polymerization is pres...
The behaviour of silica supported metallocene catalyst in the early moments of olefin polymerization...
Polymer particle growth in the early stages of olefin polymerization has been investigated using met...
A study was performed to improve the model for metallocene catalyzed polyolefin polymerization in fl...
Kinetics-based differences in the early stage fragmentation of two structurally analogous silica-sup...
A model-based approach was employed to reveal the elementary steps and the corresponding rate consta...
Coupled single-particle growth and kinetics modeling for styrene polymerization over silica-supporte...
The early stages (from less than 1s to few minutes) of catalytic olefin polymerization are still fai...