Season\u27s influence on the relationship between mass concentrations of sulphur dioxide and sulphate in the air

Studiran je odnos masenih koncentracija (p) sumpor-dioksida i sulfata u prirodnim uvjetima, tj. u dvije gradske sredine s različitim razinama atmosferskog onečišćenja tijekom zimskog i ljetnog razdoblja. Na svakom mjernom mjestu tijekom sezone sakupljeno je i analizirano pedesetak uzoraka sumpor-dioksida, dima·i lebdećih čestica. U uzorcima lebdećih čestica određivana je ukupna masena koncentracija lebdećih čestica, sulfata, kalcija, olova, željeza, mangana i bakra. Studirana je korelacija po sezonama između masenih koncentracija sulfata i sumpor-dioksida, lebdećih čestica, dima, te pojedinih komponenata lebdećih čestica. Dobivena je dobra korelacija između masenih koncentracija sulfata i lebdećih čestica. Razine masenih koncentracija sumpor-dioksida, dima, sulfata i lebdećih čestica značajno su više tijekom zimskog razdoblja u obim sredinama. Na obim je mjestima dobiven gotovo jednak prosječni maseni udjel (w) sulfata (oko 10) u lebdećim česticama i tijekom zimskog i ljetnog razdoblja. Izračunate jednadžbe regresije za odnos između sulfatnog S i ukupnog S (sulfati i sumpor-dioksid) za ljetno i zimsko razdoblje međusobno se razlikuju. Izgleda da se taj sezonski utjecaj na odnos masenih koncentracija sumpor-dioksida i sulfata može dovesti u vezu s različitim porijeklom i različitim razinama masenih koncentracija lebdećih čestica u zraku.The relationship between sulphur dioxide and sulphate was studied in natural conditions, in two urban areas with different levels of air pollution during the winter and summer periods. About fifty samples of sulphur dioxide, smoke and suspended particulates were collected and analysed on each measuring site during the season. In the sample of suspended particulates the total mass concentration of suspended particulates, sulphate, calcium, lead, iron, manganese and copper was determined. The correlation between sulphate and sulphur dioxide, suspended particulates, smoke and some suspended particulate\u27s components was studied by seasons. A good correlation was found between the concentration of sulphate and suspended particulates. The concentration levels of sulphur dioxide, smoke, sulphate and suspended particulates were significantly higher during the winter period in both areas. On both locations the average mass fraction of sulphate (about 10%) in suspended particulates was nearly the same during the winter and summer periods. The calculated equation regressions for the relationship between sulphate S and total S (sulphate and sulphur dioxide) for the summer and winter period are reciprocally different. It seems that the season\u27s influence on the relationship between sulphur dioxide and sulphate might be due to a different origin and different levels of suspended particulates in the air