Deprotonation of the ionogenic tetradentate ligand 6,6′-bis(1H-tetrazol-5-yl)-2,2′-bipyridine [H2bipy(ttr)2] in the presence of FeII in solution has afforded an anionic mononuclear complex and a neutral two-dimensional coordination polymer formulated as, respectively, NEt3H{Fe[bipy(ttr)2][Hbipy(ttr)2]}·3MeOH (1) and {Fe[bipy(ttr)2]}n (2). The anions [Hbipy(ttr)2]− and [bipy(ttr)2]2– embrace the FeII centers defining discrete molecular units 1 with the FeII ion lying in a distorted bisdisphenoid dodecahedron, a rare example of octacoordination in the coordination environment of this cation. The magnetic behavior of 1 shows that the FeII is high-spin, and its Mössbauer spectrum is characterized by a relatively large average quadrupole splitti...
The spin crossover behaviour of a new class of Fe II coordination polymers [Fe(phtptrz) 3]I 2 (1), [...
Two solvent-free two-dimensional (2D) coordination polymers, <sup>2</sup><sub>∞</sub>[Fe(ptim)<sub>...
Two new iron(II) complexes of formula [Fe(L2)](tcm)2·2H2O (1) and [Fe(L2)][Ni(CN)4]·H2O (2) {L2 = 1,...
Deprotonation of the ionogenic tetradentate ligand 6,6'-bis(1H-tetrazol-5-yl)-2,2'-bipyridine [H2bip...
"This document is the Accepted Manuscript version of a Published Work that appeared in final form in...
Deprotonation of the ionogenic tetradentate ligand 6,6′-bis(1<i>H</i>-tetrazol-5-yl)-2,2′-bipyridin...
The reaction of 1,3-bis(tetrazol-1-yl)-2-propanol (btzpol) with Fe(BF4)2 Æ 6H2O in acetonitrile yiel...
The reaction of 1,3-bis(tetrazol-1-yl)-2-propanol (btzpol) with Fe(BF4)(2) center dot 6H(2)O in acet...
The tetrapyridyl ligand bbpya (bbpya=N,N-bis(2,2′-bipyrid-6-yl)amine) and its mononuclear coordinati...
A series of bulky substituted bipyridine-related iron(II) complexes [Fe(H2Bpz2)2(L)] (pz = pyrazolyl...
International audienceA series of bulky substituted bipyridine-related iron(II) complexes [Fe(HBpz)(...
The tetrapyridyl ligand bbpya (bbpya=N,N-bis(2,2'-bipyrid-6-yl)amine) and its mononuclear coordinati...
A tetranuclear iron grid-type spin crossover complex, [FeII4(HL)4](BF4)4·6H2O (1) (H2L = 2-(4-hydrox...
Heteroleptic complexes [Fe(bpte)(bim)]X<sub>2</sub> and [Fe(bpte)(xbim)]X<sub>2</sub> (bpte = ...
With a new bis-azole molecular fragment (Htt) bearing 1,2,4-triazole and tetrazole, a mononuclear co...
The spin crossover behaviour of a new class of Fe II coordination polymers [Fe(phtptrz) 3]I 2 (1), [...
Two solvent-free two-dimensional (2D) coordination polymers, <sup>2</sup><sub>∞</sub>[Fe(ptim)<sub>...
Two new iron(II) complexes of formula [Fe(L2)](tcm)2·2H2O (1) and [Fe(L2)][Ni(CN)4]·H2O (2) {L2 = 1,...
Deprotonation of the ionogenic tetradentate ligand 6,6'-bis(1H-tetrazol-5-yl)-2,2'-bipyridine [H2bip...
"This document is the Accepted Manuscript version of a Published Work that appeared in final form in...
Deprotonation of the ionogenic tetradentate ligand 6,6′-bis(1<i>H</i>-tetrazol-5-yl)-2,2′-bipyridin...
The reaction of 1,3-bis(tetrazol-1-yl)-2-propanol (btzpol) with Fe(BF4)2 Æ 6H2O in acetonitrile yiel...
The reaction of 1,3-bis(tetrazol-1-yl)-2-propanol (btzpol) with Fe(BF4)(2) center dot 6H(2)O in acet...
The tetrapyridyl ligand bbpya (bbpya=N,N-bis(2,2′-bipyrid-6-yl)amine) and its mononuclear coordinati...
A series of bulky substituted bipyridine-related iron(II) complexes [Fe(H2Bpz2)2(L)] (pz = pyrazolyl...
International audienceA series of bulky substituted bipyridine-related iron(II) complexes [Fe(HBpz)(...
The tetrapyridyl ligand bbpya (bbpya=N,N-bis(2,2'-bipyrid-6-yl)amine) and its mononuclear coordinati...
A tetranuclear iron grid-type spin crossover complex, [FeII4(HL)4](BF4)4·6H2O (1) (H2L = 2-(4-hydrox...
Heteroleptic complexes [Fe(bpte)(bim)]X<sub>2</sub> and [Fe(bpte)(xbim)]X<sub>2</sub> (bpte = ...
With a new bis-azole molecular fragment (Htt) bearing 1,2,4-triazole and tetrazole, a mononuclear co...
The spin crossover behaviour of a new class of Fe II coordination polymers [Fe(phtptrz) 3]I 2 (1), [...
Two solvent-free two-dimensional (2D) coordination polymers, <sup>2</sup><sub>∞</sub>[Fe(ptim)<sub>...
Two new iron(II) complexes of formula [Fe(L2)](tcm)2·2H2O (1) and [Fe(L2)][Ni(CN)4]·H2O (2) {L2 = 1,...