Multiple strain-induced phase transitions in LaNiO3 thin films

Weber, M.C. et al.Strain effects on epitaxial thin films of LaNiO3 grown on different single crystalline substrates are studied by Raman scattering and first-principles simulation. New Raman modes, not present in bulk or fully-relaxed films, appear under both compressive and tensile strains, indicating symmetry reductions. Interestingly, the Raman spectra and the underlying crystal symmetry for tensile and compressively strained films are different. Extensive mapping of LaNiO3 phase stability is addressed by simulations, showing that a variety of crystalline phases are indeed stabilized under strain which may impact the electronic orbital hierarchy. The calculated Raman frequencies reproduce the principal features of the experimental spectra, supporting the validity of the multiple strain-driven structural transitions predicted by the simulations.J.K., M.W., M.G., and J.I. acknowledge support from the National Research Fund, Luxembourg through a Pearl grant (Grant No. FNR/P12/4853155). ICMAB-CSIC authors acknowledge financial support from the Spanish Ministry of Economy and Competitiveness, through the “Severo Ochoa” Programme for Centres of Excellence in R&D (SEV-2015- 0496) and the MAT2014-56063-C2-1-R and MAT2013- 40581-P projects, and from Generalitat de Catalunya (2014 SGR 734). UB authors acknowledge financial support from the Spanish Ministry of Economy and Competitiveness, project MAT2013-41506-P and from Generalitat de Catalunya (2014 SGR 672).Peer reviewe