Strengthening by intermetallic nanoprecipitation in Fe-Cr-Al-Ti alloy

The strengthening mechanism observed during ageing at temperatures of 435 and 475 °C in the oxide dispersion strengthened (ODS) Fe-Cr-Al-Ti system has been investigated. Atom probe tomography (APT) and high-resolution transmission electron microscopy (HRTEM) analyses determined that the alloy undergoes simultaneous precipitation of Cr-rich (α′ phase) and nanoscale precipitation of TiAl-rich intermetallic particles (β′ phase). APT indicated that the composition of the intermetallic β′ phase is FeAlTiCr, and the evolving composition of α′ phase with ageing time was also determined. The results obtained from HRTEM analyses allow us to confirm that the β′ precipitates exhibit a cubic structure and hence their crystallography is related to the Heusler-type FeAlTi (L2) structure. The strengthening could be explained on the basis of two hardening effects that occur simultaneously: the first is due to the α-α′ phase separation through the modulus effect, and the second mechanism is due to the interaction of nanoscale β′ particles with dislocations.PM 2000™ is a trademark of Plansee GmbH. LEAP® is a registered trademark of CAMECA Instruments Inc. CC and JC acknowledge financial support to Spanish Ministerio de Economia y Competitividad (MINECO) through in the form of a Coordinate Project (MAT2013-47460-C5-1-P). Atom probe tomography (MKM) was supported through a user project supported by ORNL's Center for Nanophase Materials Sciences (CNMS), which is sponsored by the Scientific User Facilities Division, Office of Basic Energy Sciences, U.S. Department of Energy.Peer Reviewe