Two M8L12 cubic coordination cages, as desolvated crystalline powders, preferentially adsorb CO2 over N2 with ideal selectivity CO2/N2 constants of 49 and 30 at 298 K. A binding site for CO2 is suggested by crystallographic location of CS2 within the cage cavity at an electropositive hydrogen-bond donor site, potentially explaining the high CO2/N2 selectivity compared to other materials with this level of porosity
Improved carbon capture materials are crucial for managing the CO2 level in the atmosphere. The past...
Due to their high surface areas and structural tunability, porous metal-organic materials, MOMs, hav...
Nitrogen dioxide (NO2) is a major air pollutant causing significant environmental and health problem...
Two M8L12 cubic coordination cages, as desolvated crystalline powders, preferentially adsorb CO2 ove...
A new microporous metal dicyanamide cluster, Co(hmt)(dca)2 (hmt: hexamethylenetetramine, dca: dicyan...
The {Cr8 } metallacrown [CrF(O2 C(t) Bu)2 ]8 , containing a F-lined internal cavity, shows high sele...
PCM-14 is a dense coordination polymer formed from Ca(II) and an unusual organophosphonium ligand. T...
Coordination-driven assembly has been widely successful in the synthesis of metallocages and used fo...
Funding: EPSRCThe structure of dehydrated calcined ECR-18, synthetic paulingite, topology type PAU, ...
peer-reviewedInspired by the structure of carbonic anhydrase, we developed a robust ultramicroporous...
Metal-organic frameworks (MOFs) have been postulated for years as industrially achievable materials ...
A metal organic framework Cu(tpt)BF4·¾H2O was synthesized as a potential carbon capture material, wi...
Metal–organic frameworks (MOFs) have been postulated for years as industrially achievable materials ...
Thermal treatment of hexaazatriphenylene-hexacarbonitrile (HAT-CN) in the temperature range from 500...
The metallocage, UMC-1, has a trigonal bipyramid inter-cage composed of Zr-cationic cluster and orga...
Improved carbon capture materials are crucial for managing the CO2 level in the atmosphere. The past...
Due to their high surface areas and structural tunability, porous metal-organic materials, MOMs, hav...
Nitrogen dioxide (NO2) is a major air pollutant causing significant environmental and health problem...
Two M8L12 cubic coordination cages, as desolvated crystalline powders, preferentially adsorb CO2 ove...
A new microporous metal dicyanamide cluster, Co(hmt)(dca)2 (hmt: hexamethylenetetramine, dca: dicyan...
The {Cr8 } metallacrown [CrF(O2 C(t) Bu)2 ]8 , containing a F-lined internal cavity, shows high sele...
PCM-14 is a dense coordination polymer formed from Ca(II) and an unusual organophosphonium ligand. T...
Coordination-driven assembly has been widely successful in the synthesis of metallocages and used fo...
Funding: EPSRCThe structure of dehydrated calcined ECR-18, synthetic paulingite, topology type PAU, ...
peer-reviewedInspired by the structure of carbonic anhydrase, we developed a robust ultramicroporous...
Metal-organic frameworks (MOFs) have been postulated for years as industrially achievable materials ...
A metal organic framework Cu(tpt)BF4·¾H2O was synthesized as a potential carbon capture material, wi...
Metal–organic frameworks (MOFs) have been postulated for years as industrially achievable materials ...
Thermal treatment of hexaazatriphenylene-hexacarbonitrile (HAT-CN) in the temperature range from 500...
The metallocage, UMC-1, has a trigonal bipyramid inter-cage composed of Zr-cationic cluster and orga...
Improved carbon capture materials are crucial for managing the CO2 level in the atmosphere. The past...
Due to their high surface areas and structural tunability, porous metal-organic materials, MOMs, hav...
Nitrogen dioxide (NO2) is a major air pollutant causing significant environmental and health problem...