Oxidative activation of wood fibers for the manufacture of medium-density fiberboard (MDF)

The aim of this thesis work was to study the possibilities of radical formation in wood fiber surfaces to enable direct fiber-to-fiber adhesion by radical-based reactions in the manufacture of fibreboard, particularly medium-density fiberboard (MDF). The fibers were produced by defibration at high temperatures. Radical formation was achieved by treatment with laccase, treatment with Fenton's reagent, or gamma-irradiation. High-temperature defibration was found to cause cleavage of interunit beta-aryl ether linkages of lignin, resulting in formation of mechanoradicals and phenolic hydroxyl groups. The proportion of water-extractable low-molecular weight lignin and hemicelluloses present in the fibers increased with an increase in defibration temperature. In the laccase treatment of fibers in water suspension, much more radicals were formed in hardwood than in softwood fibers for fibers produced at equal temperature. Radical formation increased with increasing defibration temperature. The treatment of fibers with Fenton's reagent in water suspension resulted in the formation of similar numbers of radicals in hardwood and softwood fibers. Radical formation increased with increasing defibration temperature but not so drastically as with laccase treatments. Also the gamma-irradiated fibers contained large numbers of radicals. Their content increased as a function of increasing defibration temperature and was higher for hardwood than for softwood fibers. The internal bond strength (IB) of fiberboards made from fibers treated with laccase or Fenton's reagent in the defibrator blowline improved with increasing defibration temperature. The IB of boards made from laccase-treated fibers correlated with the number of radicals formed in the fibers on laccase treatment in water suspension, indicating that adhesion in the boards was largely due to reactions of radicals on the fiber surfaces. The IB of boards made from fibers treated with Fenton's reagent also correlated with the radical content of the fibers, but this relationship was not as strong as with the laccase treatments. This suggests that bonding mechanisms other than radical coupling may have contributed significantly to adhesion. Gamma-irradiation of fibers before their fabrication into boards resulted in a marked increase in board IB, indicating that radicals play a significant role in the adhesion of boards made from gamma-irradiated fibers.reviewe