Experimental and DFT study on the indiummediated synthesis of benzophenones via arylstannanes
- Lo Fiego, Marcos Jacinto
- Dorn, Viviana B.
- Badajoz, Mercedes A.
- Lockhart, Maria T.
- Chopa, Alicia B.
DOIAbstract
Experimental results of the solvent-free, indium-promoted reaction of aroyl chlorides with arylstannanes showed a narrow scope; its efficiency depends both on the extent of methylation in the latter and on the nature, number and position of the substituents in the former. With the purpose of explaining experimental results, a theoretical analysis with DFT methods was performed for a set of selected cases.Fil: Lo Fiego, Marcos Jacinto. Universidad Nacional del Sur. Departamento de Quimica. Instituto de Invest.en Quimica Organica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; ArgentinaFil: Dorn, Viviana B.. Universidad Nacional del Sur. Departam...
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