Tethered η5-oxocyclohexadienyl piano-stool ruthenium(II) complexes: A new class of catalysts?
- Kechaou-Perrot, M.
- Vendier, L.
- Bastin, S.
- Sotiropoulos, Jean-Marc
- Miqueu, K.
- Menéndez-Rodríguez, L.
- Crochet, P.
- Cadierno, V.
- Igau, A.
DOIAbstract
International audienceThe straightforward synthesis of tethered η5-oxocyclohexadienyl Ru(II) complexes is presented. Pioneering results in catalysis show that these original half-sandwich Ru(II) complexes allow the effective isomerization of allylic alcohols under mild conditions without further additives; η5-oxocyclohexadienyl ruthenium complexes may be considered as a new class of catalysts. © 2014 American Chemical Society
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