Secondary Phosphine Oxide-Gold(I) Complexes and Their First Application in Catalysis
- Schroeder, Felix
- Tugny, Coralie
- Salanouve, Elise
- Clavier, Hervé
- Giordano, Laurent
- Moraleda, Delphine
- Gimbert, Yves
- Mouriès-Mansuy, Virginie
- Goddard, Jean-Philippe
- Fensterbank, Louis
DOIAbstract
International audienceA series of new secondary phosphine oxide (SPO)-gold(1) complexes have been synthesized and characterized by X-ray crystallography. Complexes exhibited dimeric structures interconnected by O-H center dot center dot center dot Cl hydrogen bonds. Their first use in homogeneous catalysis is reported and suggests a broad field of application in prototypical enyne cycloisomerization and hydroxy- and methoxycyclization reactions
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