Add to ORKGThiopheneacetylene (RCCH; R3-Th, 2-Th; ThC4H3S) adds across the Se–Se bond of (CO)6Fe2(m-Se2) at room temperature in methanol solvent containing sodium acetate to yield the adduct (CO)6Fe2{m-SeC(H)C(R)Se} (R3-Th (1); 2-Th (3)) and the double butterfly complex [{(CO)6Fe2Se2}2{m-C(H)–C(R)}] (R3-Th (2); 2-Th (4)). Compounds 1–4 were character-ized by spectroscopic techniques (IR and 1H-, 13C- and 77Se-NMR) and their composition confirmed by elemental analysis. Structures of 2 and 4 were further confirmed by single-crystal X-ray diffraction study
At room temperature, the double butterfly complex [{(CO)6Fe2(mu-Se)2}2(C(Ph)-C(H)] reacted with Pt(C...
The room-temperature reaction of the mixed-chalcogenide complex Fe2(CO)6(mu-STe) with the diacetylen...
The diacetylenic adducts, Fe2(CO)6{μ-EC(H) = C(C ≡ CMe)E'} (E = E', E E; E, E' = S, Se, T...
Room temperature stirring of (CO)(6)Fe-2(mu-EE') with 2-thiopheneacetylene (2-ThC=CH) in methanol co...
When acetylene gas was bubbled through methanol solutions containing the mixed-chalcogenide compound...
When acetylene gas was bubbled through methanol solutions containing the mixed-chalcogenide compound...
The new acetylenic derivatives [(CO)6Fe2{μ-SeC(H)-C(H)Se}] and [{(CO)6Fe2Se2}2{μ-C(H)-C(H)}] have be...
Stepwise addition of phenylacetylene and Pt(PPh3)2 across the Se-Se bond of [Fe2(CO)6(mu-Se2)] can b...
Bubbling acetylene gas slowly through a methanol solution of [(CO)6Fe2{μ-SSe}] containing sodium ace...
Bubbling acetylene gas slowly through a methanol solution of [(CO)(6)Fe-2{mu-SSe}] containing sodium...
The new acetylenic derivatives [(CO)(6)Fe-2{mu-SeC(H)=C(H)Se}] and [{(CO)(6)Fe2Se2}(2){mu-C(H)-C(H)}...
The compounds (CO)6Fe2Se2{μ-HC=C(C=CR)} (R=Me (1) or n-Bu (2) and {(CO)6Fe2Se2}2{μ-HC=C(C=CR)} (R=Me...
At room temperature, the double butterfly complex [{(CO)6Fe2(μ-Se)2}2,(C(Ph)-C(H)] reacted with Pt(C...
From the room temperature reaction of the transition metal alkynyl Fischer carbene complexes (CO)5M=...
From the room-temperature reaction of the mixed-chalcogenide compound Fe-2(CO)(6)(mu-SeTe) with phen...
At room temperature, the double butterfly complex [{(CO)6Fe2(mu-Se)2}2(C(Ph)-C(H)] reacted with Pt(C...
The room-temperature reaction of the mixed-chalcogenide complex Fe2(CO)6(mu-STe) with the diacetylen...
The diacetylenic adducts, Fe2(CO)6{μ-EC(H) = C(C ≡ CMe)E'} (E = E', E E; E, E' = S, Se, T...
Room temperature stirring of (CO)(6)Fe-2(mu-EE') with 2-thiopheneacetylene (2-ThC=CH) in methanol co...
When acetylene gas was bubbled through methanol solutions containing the mixed-chalcogenide compound...
When acetylene gas was bubbled through methanol solutions containing the mixed-chalcogenide compound...
The new acetylenic derivatives [(CO)6Fe2{μ-SeC(H)-C(H)Se}] and [{(CO)6Fe2Se2}2{μ-C(H)-C(H)}] have be...
Stepwise addition of phenylacetylene and Pt(PPh3)2 across the Se-Se bond of [Fe2(CO)6(mu-Se2)] can b...
Bubbling acetylene gas slowly through a methanol solution of [(CO)6Fe2{μ-SSe}] containing sodium ace...
Bubbling acetylene gas slowly through a methanol solution of [(CO)(6)Fe-2{mu-SSe}] containing sodium...
The new acetylenic derivatives [(CO)(6)Fe-2{mu-SeC(H)=C(H)Se}] and [{(CO)(6)Fe2Se2}(2){mu-C(H)-C(H)}...
The compounds (CO)6Fe2Se2{μ-HC=C(C=CR)} (R=Me (1) or n-Bu (2) and {(CO)6Fe2Se2}2{μ-HC=C(C=CR)} (R=Me...
At room temperature, the double butterfly complex [{(CO)6Fe2(μ-Se)2}2,(C(Ph)-C(H)] reacted with Pt(C...
From the room temperature reaction of the transition metal alkynyl Fischer carbene complexes (CO)5M=...
From the room-temperature reaction of the mixed-chalcogenide compound Fe-2(CO)(6)(mu-SeTe) with phen...
At room temperature, the double butterfly complex [{(CO)6Fe2(mu-Se)2}2(C(Ph)-C(H)] reacted with Pt(C...
The room-temperature reaction of the mixed-chalcogenide complex Fe2(CO)6(mu-STe) with the diacetylen...
The diacetylenic adducts, Fe2(CO)6{μ-EC(H) = C(C ≡ CMe)E'} (E = E', E E; E, E' = S, Se, T...