A miktoarm star-shaped copolymer, with one polystyrene arm (Mw = 198 kg/mol) and three polyisoprene arms (Mw = 51 kg/mol) (PSPI3), was rigorously characterized by temperature gradient interaction chromatography (TGIC). The polymer was prepared by linking active chain ends of precursor polymers to tetrachlorosilane as the linking agent, and the precursor polymers were prepared by anionic polymerization. The crude product was purified by fractional precipitation to remove the byproducts and the excess reagents. Size exclusion chromatography (SEC) analysis shows a narrow single elution peak whose molecular weight and composition are in good agreement with the predicted values in experimental precision. Therefore, it appears on the basis of con...
A new method, temperature gradient interaction chromatography(TGIC) is employed for the characteriza...
Liquid chromatography at the chromatographic critical condition has drawn much attention as an attra...
One of the current trends in polymer chemistry is to improve the properties of common polymers in or...
Temperature gradient interaction chromatography (TGIC) was applied for the separation of a complex m...
We report the characterization of polystyrene by temperature-gradient interaction chromatography (TG...
Thermodynamic principles and some applications of the temperature gradient interaction chromatograph...
Owing to their low polydispersity and their well controlled molecular architecture, 3-arms stars pol...
An exact polystyrene-graft-polyisoprene (PS-g-PI) synthesized by iterative anionic polymerization an...
Temperature gradient interaction chromatography (TGIC) analysis of polyisoprene (PI) is reported. PI...
Size exclusion chromatography (SEC) coupled with triple detection (TD) method is widely used for bra...
We analyzed various miktoarm star copolymers of the PS(PI)<sub><i>x</i></sub> type (<i>x</i> = 2, 3...
Temperature gradient interaction chromatography (TGIC) was applied for the separation of stereoregul...
The structural details of a set of highly entangled H-shaped polybutadienes (PBDs) prepared by anion...
Most heterogeneities of polymers with respect to different structural features cannot be resolved by...
International audienceSeparation of parent homopolymers, polystyrene and poly(ethylene oxide), from ...
A new method, temperature gradient interaction chromatography(TGIC) is employed for the characteriza...
Liquid chromatography at the chromatographic critical condition has drawn much attention as an attra...
One of the current trends in polymer chemistry is to improve the properties of common polymers in or...
Temperature gradient interaction chromatography (TGIC) was applied for the separation of a complex m...
We report the characterization of polystyrene by temperature-gradient interaction chromatography (TG...
Thermodynamic principles and some applications of the temperature gradient interaction chromatograph...
Owing to their low polydispersity and their well controlled molecular architecture, 3-arms stars pol...
An exact polystyrene-graft-polyisoprene (PS-g-PI) synthesized by iterative anionic polymerization an...
Temperature gradient interaction chromatography (TGIC) analysis of polyisoprene (PI) is reported. PI...
Size exclusion chromatography (SEC) coupled with triple detection (TD) method is widely used for bra...
We analyzed various miktoarm star copolymers of the PS(PI)<sub><i>x</i></sub> type (<i>x</i> = 2, 3...
Temperature gradient interaction chromatography (TGIC) was applied for the separation of stereoregul...
The structural details of a set of highly entangled H-shaped polybutadienes (PBDs) prepared by anion...
Most heterogeneities of polymers with respect to different structural features cannot be resolved by...
International audienceSeparation of parent homopolymers, polystyrene and poly(ethylene oxide), from ...
A new method, temperature gradient interaction chromatography(TGIC) is employed for the characteriza...
Liquid chromatography at the chromatographic critical condition has drawn much attention as an attra...
One of the current trends in polymer chemistry is to improve the properties of common polymers in or...