We report anovel catalytic conversion of biomass-derived furans and alcohols to aromatics over zeolite catalysts.Aromatics are formed via Diels–Alder cycloaddition withethylene,whichisproduced in situ from ethanol dehydration.The use of liquid ethanol instead of gaseous ethylene,asthesource of dienophile in this one-pot synthesis,makes thearomatics production muchsimpler and renewable,circum-venting the use of ethylene at high pressure.More importantly,both our experiments and theoretical studies demonstrate thatthe use of ethanol instead of ethylene,results in significantlyhigher rates and higher selectivity to aromatics,due to loweractivation barriers over the solid acid sites.Synchrotron-diffraction experiments and proton-affinity calcul...
Taking into account that the transformation of biomass-derived 2,5-dimethylfuran (DMF) to p-xylene i...
The catalytic Diels–Alder cycloaddition–dehydration (DACD) reaction of furanics with ethylene is a p...
Herein we report a mechanistic study of aromatization of furanics, as model compounds for cellulosic...
We report a novel catalytic conversion of biomass-derived furans and alcohols to aromatics over zeol...
The conversion of lignocellulosic biomass to renewable fuels and chemicals has attracted significant...
Due to its low cost and availability, lignocellulosic biomass is receiving significant attention wor...
Herein, we report a synthetic strategy to convert biomass-derived unsubstituted furan to aromatics a...
Anno 2023, mankind must strive towards a more sustainable chemical industry; one that does not solel...
Lobo, Raul F.Chemicals provide most of the material and energy for mankind. A majority of chemicals ...
Vlachos, Dionisios G.The development of strategies to convert renewable feedstocks into fuels and ch...
In this paper, we study the production of aromatic hydrocarbons by co-feeding furans and methanol in...
Increasing demand for renewable and domestic energy and materials has led to an accelerated research...
Doren, Douglas J.Economic, environmental and political considerations have led to gradually replacem...
The conversion of furan (a model of cellulosic biomass) over ZSM-5 was studied in a TGA/TPD-MS syste...
The conversion of furan (a model of cellulosic biomass) over HZSM-5 was investigated in a thermograv...
Taking into account that the transformation of biomass-derived 2,5-dimethylfuran (DMF) to p-xylene i...
The catalytic Diels–Alder cycloaddition–dehydration (DACD) reaction of furanics with ethylene is a p...
Herein we report a mechanistic study of aromatization of furanics, as model compounds for cellulosic...
We report a novel catalytic conversion of biomass-derived furans and alcohols to aromatics over zeol...
The conversion of lignocellulosic biomass to renewable fuels and chemicals has attracted significant...
Due to its low cost and availability, lignocellulosic biomass is receiving significant attention wor...
Herein, we report a synthetic strategy to convert biomass-derived unsubstituted furan to aromatics a...
Anno 2023, mankind must strive towards a more sustainable chemical industry; one that does not solel...
Lobo, Raul F.Chemicals provide most of the material and energy for mankind. A majority of chemicals ...
Vlachos, Dionisios G.The development of strategies to convert renewable feedstocks into fuels and ch...
In this paper, we study the production of aromatic hydrocarbons by co-feeding furans and methanol in...
Increasing demand for renewable and domestic energy and materials has led to an accelerated research...
Doren, Douglas J.Economic, environmental and political considerations have led to gradually replacem...
The conversion of furan (a model of cellulosic biomass) over ZSM-5 was studied in a TGA/TPD-MS syste...
The conversion of furan (a model of cellulosic biomass) over HZSM-5 was investigated in a thermograv...
Taking into account that the transformation of biomass-derived 2,5-dimethylfuran (DMF) to p-xylene i...
The catalytic Diels–Alder cycloaddition–dehydration (DACD) reaction of furanics with ethylene is a p...
Herein we report a mechanistic study of aromatization of furanics, as model compounds for cellulosic...