Tensiometric, IR- and 19F-NMR Analysis of Nafion Solutions for PEMFCs and PEMELs

Tensiometric, IR- and 19F-NMR analysis of Nafion® solutions for PEMFCs and PEMELs A. Schulza*, N. Luehmannb, M. Staehlera, W. Luekea, W. Lehnerta,ca) Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research,IEK-3: Electrochemical Process Engineering, 52425 Jülich, Germanyb) Forschungszentrum Jülich GmbH, Jülich Centre for Neutron Science JCNS 1/ICS-1: Institute of Complex Systems, 52425 Jülich, Germanyc) Modeling in Electrochemical Process Engineering, RWTH Aachen University, Germany* Corresponding author; tel.: +49 2461 61 8965; fax: +49 2461 61 6695; e-mailaddress: a.schulz@fz-juelich.deAbstractIn the construction of polymer electrolyte membrane fuel cells (PEMFCs) and polymer electrolyte membrane electrolyzers (PEMELs), Nafion® (sulfonated tetrafluorethylene) is used as a membrane material and as proton conductor in the porous catalysts layers of membrane electrode assemblies (MEAs). Efficiency can be increased and costs reduced by optimizing and controlling the porous catalyst layer in MEAs. It is important to understand the polymer properties, which can be achieved by using different solutions and varying concentrations of one mixture for manufacturing the dispersion. Furthermore, the findings are of particular importance for the coating process. The efficiency of the PEMFCs and PEMELs depends on the number of active centers in the porous catalyst layer. The formation of the triple phase boundary is of great importance. This can be ensured by controlling the structural properties of the dispersion. Thereby, the static and dynamic surface tensions are analyzed. Surface tension and interfacial tension are necessary for understanding the coating process and adhesion to a transfer layer. The complex system was simplified and research on the surface properties performed with an aqueous Nafion® solution in an alcohol concentration series. Hence, the only aspect that changed was the alcohol, while the dynamic surface tension was measured with a bubble pressure tensiometer (BP100, KRÜSS GmbH). The static surface tension and interfacial surface tension were carried out with a force tensiometer (K100, KRÜSS GmbH) after Wilhelmy plate respectively the duNouy Ring method. In addition the solution was analyzed by means of IR- and 19F-NMR- spectroscopy. It will be demonstrated in this contribution that the static and dynamic surface tensions differ significantly at lower alcohol concentrations in solution series with and without Nafion®. While at higher alcohol concentrations the static surface tension between both series is similar, the dynamic surface tension shows a different trend with varied bubble age. This can be explained by the interaction between alcohol and Nafion®. In accordance with the previous interface outcomes, the 19F-NMR- and IR- spectra are analyzed. According to the first results, it is also apparent that there are interactions between Nafion® and alcohol. The application of these methods provides an understanding of the interaction between the molecules in the catalyst dispersions. This information is essential for understanding the interactions between the components of catalyst dispersion during electrode manufacturing