The defect structure of cubic fluorite structured yttria-stabilized zirconia (ZrO2)(1-x)(Y2O3)(x) has been investigated over the composition range 0.100(3)less than or equal to x less than or equal to 0.241 (10) and temperatures T(K) up to 2780(10) K, using single-crystal specimens. Analysis of neutron and x-ray diffraction data, including both Bragg and coherent diffuse scattering components, has identified three principal types of defects within the fluorite lattice. At low yttria concentrations (xsimilar to 1000 K and give rise to the high ionic conductivity of the material. In light of these observations, we propose that the anomalous decrease in the ionic conductivity with increasing x is a consequence of the decreasing mobility of the...
The cubic fluorite-type solid solution of ZrO₂ containing 15 mole % CaO has been prepared by the hot...
The degradation behavior of yttria-stabilized zirconia by thermal aging was investigated in terms of...
Polarizable interaction potentials, parametrized using ab initio electronic structure calculations, ...
The defect structure of cubic fluorite structured yttria-stabilized zirconia (ZrO2)(1-x)(Y2O3)(x) ha...
Extensive regions of cubic fluorite solid solution formation are observed in the Y2O3-ZrO2, Y2O3-ZrO...
Present knowledge of transport of charge and mass in fluorite oxides is based on results from polycr...
The influence of local ordering of the anion vacancies and cation-anion vacancy interactions on the ...
The influence of local ordering of the anion vacancies and cation-anion vacancy interactions on the ...
The static defect structure of the oxygen ion conductor Y203 stabilized zirconia has been studied at...
The influence of local ordering of the anion vacancies and cation-anion vacancy interactions on the ...
A comprehensive study of 8 mol% yttria-stabilised zirconia has been made between 150 and 1000 degree...
The transport of charge and mass in oxide single crystals with fluorite structure were investigated ...
The Zr0.5-0.5xY0.5+0.25xNb0.25xO1.75 solid solution possesses an anion-deficient fluorite structure ...
In the ZrO2-CaO system cubic solid solutions of the fluorite-type structure are formed between 12 an...
Oxygen ion conductors with most symmetrical structures such as fluorite- and perovskite-related phas...
The cubic fluorite-type solid solution of ZrO₂ containing 15 mole % CaO has been prepared by the hot...
The degradation behavior of yttria-stabilized zirconia by thermal aging was investigated in terms of...
Polarizable interaction potentials, parametrized using ab initio electronic structure calculations, ...
The defect structure of cubic fluorite structured yttria-stabilized zirconia (ZrO2)(1-x)(Y2O3)(x) ha...
Extensive regions of cubic fluorite solid solution formation are observed in the Y2O3-ZrO2, Y2O3-ZrO...
Present knowledge of transport of charge and mass in fluorite oxides is based on results from polycr...
The influence of local ordering of the anion vacancies and cation-anion vacancy interactions on the ...
The influence of local ordering of the anion vacancies and cation-anion vacancy interactions on the ...
The static defect structure of the oxygen ion conductor Y203 stabilized zirconia has been studied at...
The influence of local ordering of the anion vacancies and cation-anion vacancy interactions on the ...
A comprehensive study of 8 mol% yttria-stabilised zirconia has been made between 150 and 1000 degree...
The transport of charge and mass in oxide single crystals with fluorite structure were investigated ...
The Zr0.5-0.5xY0.5+0.25xNb0.25xO1.75 solid solution possesses an anion-deficient fluorite structure ...
In the ZrO2-CaO system cubic solid solutions of the fluorite-type structure are formed between 12 an...
Oxygen ion conductors with most symmetrical structures such as fluorite- and perovskite-related phas...
The cubic fluorite-type solid solution of ZrO₂ containing 15 mole % CaO has been prepared by the hot...
The degradation behavior of yttria-stabilized zirconia by thermal aging was investigated in terms of...
Polarizable interaction potentials, parametrized using ab initio electronic structure calculations, ...