The chlorine oxyanions (ClOn-, n = 1-4) spanning oxidation states of +1 to +7 have found diverse uses over several decades as oxidants. Their uses range from making bleaching agents to propellants used in rocket fuels. The chlorine oxyanion of interest herein is chlorite (ClO2-) where the oxidation state of chlorine is +3. This oxyanion is used for the production of ClO2 in the pulp bleaching industry; however, chlorate is preferred for cost reasons (e.g. less corrosive conditions and byproducts). Therefore a catalytic method for the production of chlorine dioxide from chlorite is of interest from an industrial standpoint. Originally, the goal of the chlorite project was to synthesis a small molecule mimic of an enzyme known as chlorite dis...
Reaction bifurcation processes are often encountered in the oxidation of substrates by enzymes and g...
A new process is developed by using compound Mn as intermediate to produce Cl-2 from HCl, with the f...
The heme enzyme chlorite dismutase (Cld) catalyzes O-O bond formation as part of the conversion of t...
The oxyanions of chlorine (ClOx-, x=1-4) have diverse applications and are used in a variety of comm...
Two non-heme manganese complexes are used in the catalytic formation of chlorine dioxide from chlori...
The global production of plant biomass waste is in the order of 140 Gt per year which offers a promi...
Reaction bifurcation processes are often encountered in the oxidation of substrates by enzymes and g...
95 p.Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1982.Chloroperoxidase catalyzes the...
Chlorine dioxide (ClO2) applications to drinking water are limited by the formation of chlorite (ClO...
Reaction bifurcation processes are often encountered in the oxidation of substrates by enzymes and g...
Chlorine dioxide is a strong oxidizing agent and a powerful disinfectant. The kinetics and mechanism...
Chlorine dioxide (ClO2) has been used as an alternative to chlorine in water purification to reduce ...
A highly active catalyst, MnOx/TiO2-Al2O3, was prepared by impregnating MnOx species on TiO2-modifie...
As a powerful oxidizer, perchlorate (ClO4−) has found widespread use in many energetic materials. Ov...
A new process is developed by using compound Mn as intermediate to produce Cl 2 from HCl, with the f...
Reaction bifurcation processes are often encountered in the oxidation of substrates by enzymes and g...
A new process is developed by using compound Mn as intermediate to produce Cl-2 from HCl, with the f...
The heme enzyme chlorite dismutase (Cld) catalyzes O-O bond formation as part of the conversion of t...
The oxyanions of chlorine (ClOx-, x=1-4) have diverse applications and are used in a variety of comm...
Two non-heme manganese complexes are used in the catalytic formation of chlorine dioxide from chlori...
The global production of plant biomass waste is in the order of 140 Gt per year which offers a promi...
Reaction bifurcation processes are often encountered in the oxidation of substrates by enzymes and g...
95 p.Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1982.Chloroperoxidase catalyzes the...
Chlorine dioxide (ClO2) applications to drinking water are limited by the formation of chlorite (ClO...
Reaction bifurcation processes are often encountered in the oxidation of substrates by enzymes and g...
Chlorine dioxide is a strong oxidizing agent and a powerful disinfectant. The kinetics and mechanism...
Chlorine dioxide (ClO2) has been used as an alternative to chlorine in water purification to reduce ...
A highly active catalyst, MnOx/TiO2-Al2O3, was prepared by impregnating MnOx species on TiO2-modifie...
As a powerful oxidizer, perchlorate (ClO4−) has found widespread use in many energetic materials. Ov...
A new process is developed by using compound Mn as intermediate to produce Cl 2 from HCl, with the f...
Reaction bifurcation processes are often encountered in the oxidation of substrates by enzymes and g...
A new process is developed by using compound Mn as intermediate to produce Cl-2 from HCl, with the f...
The heme enzyme chlorite dismutase (Cld) catalyzes O-O bond formation as part of the conversion of t...