THE CONFORMATIONS OF BUTAN-2,3-DIOL BY FOURIER TRANSFORM MICROWAVE SPECTROSCOPY

$^{a}$D. Christen, L. H. Coudert, R. D. Suenram and F. J. Lovas, J. molec. Spectrosc. 172, 57-77 (1995).Author Institution: Physical and Theoretical ChemistryThe conformational landscape of butan-2,3-diol is dominated by the presence of two adjacent chiral centres and by the stabilisation from intramolecular hydrogen bonding; different conformational preferences are observed depending on whether the molecule is homo (R,R or S,S) or hetero (R,S) chiral. For instance, only the homochiral molecule may form an intramolecular hydrogen bond if the two methyl groups are anti to one another. The microwave spectrum of a conformer of (R,S) butan-2,3-diol has been recorded in a supersonic jet Fourier transform microwave spectrometer between 5 and 18 GHz. A Kraitchman analysis and evidence from an ab intio study suggest that the observed conformer is the global minimum of (R,S) butan-2,3-diol, and that it displays an intramolecular hydrogen bond. The spectrum of R,R and S,S butan-2,3,diol is believed to perturbed by a large amplitude motion, similar to that in the g'Ga conformer of ethylene $glycol^{a}$, caused by a concerted tunnelling of the two hydroxyl groups. The spectrum of the homochiral molecule was located by studying a deuterated sample. The rotational constants of the two possible mon-odeuterated species, where the tunnelling is quenched, have been extracted. We believe that the observed conformer is the global minimum of (R,R) and (S,S) butan-2,3-diol