THE PHOTOLUMINESCENCE FROM HYDROGEN-RELATED SPECIES IN COMPOSITES OF $SiO_{2}$ NANOPARTICLES

$^{a}$ Y.D. Glinka, S. H. Lin and Y. -T. Chen, Appl. Phys. Lett., 75, 778 (1999).Author Institution: Department of Chemistry, Institute of Atomic and Molecular Sciences, National Taiwan University, Academic SinicaDispersed photoluminescence (PL) spectra of silica $(SiO_{2})$ nanoparticles induced by ArF (193 nm) and Nd:YAG (266 nm) lasers have been $observed.^{a}$ PL measurements from the composites of silica nanoparticles (the primary pasticle size 7 and 15 nm) as a function of heat-treatment temperature show that the PL results from hydrogen-related species and thermally produced structural defects. The green PL exhibits a progression with spacings of $\Delta \nu \sim 630 cm^{-1}$ assigned to the bending vibration of $\equiv Si-H$ on the surface of particles. The spacings increase up to $\Delta \nu \sim 1200 cm^{-1}$ when $\equiv Si-H$ and non-bridging oxygen $(\equiv Si-O \bullet)$ form interfacial water species. The two-photon (TP) induced PL with an ArF laser excitation has also been studied. The TP-produced excitons can result in a self-trapped exciton recombination (blue band), surface hydrogen-related centers (green band) and bulk non-bridging oxygen hole centers (red band). Relaxation of free TP-produced excitons and energy transfer of the excitons to the surface and bulk defects will be discussed