OVERTONE AND COMBINATION BAND SPECTROSCOPY OF $H^{+}_{3}$

$^{a}$ Supported by the Fannic and John Hertz FoundationAuthor Institution: Department of Chemistry and Department of Astronomy and Astrophysics, The University of Chicago; Laboratoire de Spectroscopie Hertzienne, Centre d'Etudes et de Recherches Lasers et Applications, Universite de Lille; Steacie Institute for Molecular Sciences, National Research Council of Canada; Department of Chemistry and Department of Astronomy and Astrophysics, The University of ChicagoWe report our detection of $H_{3}^{+}$ rovibrational transitions between 7700 and $8200 cm^{-1}$. This work employed a New Focus external cavity tunable diode laser, a positive column discharge, and the velocity modulation technique for enhanced sensitivity to molecular ions. This frequency range encompasses transitions of the $3\nu_{2}^{1}\leftarrow 0$ and $\nu_{1}+2\nu_{2}\leftarrow 0$ bands --- the highest energy transitions studied to date. As the simplest three-atom molecule, $H_{3}^{+}$ has long served as a benchmark for ab initio calculations. We have compared our observed frequencies with our predictions, and expect that this work (along with detection of even higher overtones) will lead to better ab initio treatments of this important molecule