VIBRATIONAL SPECTRA OF $CH_{3}PCl_{2}, CH_{3}POCl_{2}$ AND $CH_{3}PSCl_{2}$

Author Institution: Department of Chemistry, University of South Carolina; Defensive Research Division, CRDL; Defensive Research Division, National Institutes of HealthThe infrared spectra of gaseous $CH_{3}PCl_{2}, CH_{3}POCl_{2}$ and $CH_{3}PSCl_{2}$ have been measured from 250 to $4000 cm^{-1}$. The Raman spectra of the liquids have been recorded and depolarization values measured. Assignment of the fundamentals based on band type, position and depolarization values will be presented