This volume contains the proceedings of the Combined 20th International Workshop on Expressiveness in Concurrency and the 10th Workshop on Structural Operational Semantics (EXPRESS/SOS 2013) which was held on 26th August, 2013 in Buenos Aires, Argentina, as an affiliated workshop of CONCUR 2013, the 24th International Conference on Concurrency Theory. The EXPRESS workshops aim at bringing together researchers interested in the expressiveness of various formal systems and semantic notions, particularly in the field of concurrency. Their focus has traditionally been on the comparison between programming concepts (such as concurrent, functional, imperative, logic and object-oriented programming) and between mathematical models of computation (...