Chemoselective oxidation of secondary alcohols using a ruthenium phenylindenyl complex

Manzini, Simone
Urbina-Blanco, César A.
Nolan, Steven

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Publication date

January 2013

DOI

10.1021/om301156v

Publisher

American Chemical Society (ACS)

ISSN

0276-7333

Citation count (estimate)

Abstract

A straightforward catalytic alcohol oxidation procedure using the recently reported complex [RuCl(PPh3)(2)(3-phenylindenyl)] (1) with KHMDS as cocatalyst, in acetone as the oxidant, is reported. Complex 1 shows remarkable chemoselectivity in oxidizing secondary alcohols to ketones

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Chemoselective oxidation of secondary alcohols using a ruthenium phenylindenyl complex

Abstract

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Chemoselective oxidation of secondary alcohols using a ruthenium phenylindenyl complex

Abstract

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