The EU Water Framework Directive (EU-WFD) requires Member States to implement measures that reduce groundwater pollution resulting from the impact of human activity (article 4). In this context, it is essential to determine the contamination not related to widespread pollution, but significantly affected by still active human influence [1] in order to reverse the sustained upward trend in pollution concentration (article 4). In the Lombardy Plain area (Northern Italy), in particular in the Functional Urban Area (FUA) of Milan (about 1000 km2), the groundwater quality status is influenced not only by soil vulnerability, which is high due to the subsoil characteristic in this area, but also by the high density of industries and anthropic ac...