The Kinetic Energy Release (KER) for various ionic species coming from two-body dissociations reactions, induced by double photoionization of CO 2, C2H2 and N2O neutral precursors of interest in planetary atmospheres, are reported. The KER distributions as a function of the VUV photon energy in the range of 30-65 eV are extracted from the coincidences spectra obtained by using tunable synchrotron radiation and electron-ion-ion coincidences coupled with ion imaging techniques. This experimental method, coupled with a computational analysis of the data based on a Monte Carlo trajectoriy simulation, allows to discuss about the probability for some ionic species to escape the upper atmosphere of Mars and Titan. In fact, the KER measured for H+,...