Synthesis and characterization of CaF2 nanocrystals

Calcium fluoride nanocrystals (CaF2) were synthesized by two different techniques namely co-precipitation and hydrothermal. The synthesized nanocrystals were characterized by powder X-ray diffraction (PXRD), Fourier transform infrared red spectroscopy (FTIR), scanning electron microscopy (SEM), optical absorption and photoluminescence (PL). The crystallite size estimated using Scherer's formula was found to be in the range 30-35 nm for nanocrystals synthesized by co-precipitation method where as in case of hydrothermally synthesized nanocrystals it is in the range 20-28 nm which is less compared to those obtained by co-precipitation method. The morphological features as studied using SEM revealed that the nanocrystals are agglomerated, crispy with porous. The SEM images of hydrothermally synthesized nanocrystals showed less agglomeration than those obtained by co-precipitation method and the images confirm the formation of nanoparticles. The optical absorption spectrum showed a strong absorption band peaked at 244 nm for nanocrystals synthesized by co-precipitation method and it is 218 nm peak in case of hydrothermally synthesized ones. The PL emission spectrum showed two prominent emission bands peaked at 330 and 600 nm when excited at 218 nm. © 2009 Elsevier B.V. All rights reserved