Correlation of structural disorder with the reversible discharge capacity of nickel hydroxide electrode

Hydrothermal treatment of a slurry of badly crystalline (βbc) nickel hydroxide at different temperatures (65-170°C) results in the progressive ordering of the structure by the step-wise elimination of disorders. Interstratification is eliminated at 140°C, while cation vacancies are eliminated at 170°C. A small percentage of stacking faults continue to persist even in 'crystalline' samples. Electrochemical investigations show that the crystalline nickel hydroxide has a very low (0.4 e/Ni) reversible charge storage capacity. An incidence of at least 15 stacking faults combined with cation vacancies is essential for nickel hydroxide to perform close to its theoretical (1 e/Ni) discharge capacity. © 2005 The Electrochemical Society. All rights reserved