Add to ORKG3-Trimethylsilylbicyclo3.2.1oct-2-ene 5 is shown to be useful in the synthesis of functionalized bicyclo3.2.1octanes. It undergoes acylation to give 3-bicyclo3.2.1oct-2-enyl ketones 6-10 without undergoing skeletal rearrangement, in contrast to the acylation of 2-trimethylsilylbicyclo2.2.1hept-2-ene 23. It can be epoxidized and the epoxysilane 21 hydrolyzes to the silyldiol 22 in normal way as against the resistance of 2-trimethylsilylbicyclo2.2.1hept-2-ene epoxide 24 towards hydrolysis
1,1-Bis(trimethylsilyloxy)ketene acetals represent useful synthetic building blocks which can be reg...
The reactions of bis (trimethylsilyl) peroxide with alkyl, vinyl, alkynyl, aromatic and heteroaromat...
Bicyclo[1.1.1]pentanes have emerged as bioisosteres, used by medicinal chemists to replace 1,4-disub...
1019-10243-Trimethylsilylbicyclo[3.2.1]oct-2-ene 5 is shown to be useful in the synthesis of functi...
(bicyclo[3.2.1]oct-2-en-3-yl)trimethylsilane (3-trimethylsilylbicyclo[3.2.1]oct-2-ene) is ...
A wide range of exo-cis-bicyclo3.3.0-2-octyl ketones are obtained by the reaction of 1-trimethylsily...
A wide range of exo-cis-bicyclo[3.3.0]-2-octyl ketones are obtained by the reaction of 1-trimethylsi...
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extr...
exo-cis-Bicyclo[3.3.0]-2-octyl ketones I [R = Me, Et, Pr, CHMe2, (CH2)10Me, Ph, CH2Ph, CH:CHPh...
Several members of two new classes of bicyclic organosilicons, 3-silabicyclo{3.2.1}octanes (3-SBO) a...
A general method for the formation of acetals using chlorotrimethylsilane has been developed. Dioxol...
Several members of two new classes of bicyclic organosilicons, 3-silabicyclo[3.2.1]octanes (3-SBO) a...
Trimethylsilyl enol ethers of 1,3-diketones are generated “in situ†or obtained in high iso...
The preparation of the titte compounds is reported starting from the corresponding bromo derivatives...
The 5,6,9,10-tetrahydro-7,8-benzocyclooctenedione 4 has been synthesized through fragmentation of a ...
1,1-Bis(trimethylsilyloxy)ketene acetals represent useful synthetic building blocks which can be reg...
The reactions of bis (trimethylsilyl) peroxide with alkyl, vinyl, alkynyl, aromatic and heteroaromat...
Bicyclo[1.1.1]pentanes have emerged as bioisosteres, used by medicinal chemists to replace 1,4-disub...
1019-10243-Trimethylsilylbicyclo[3.2.1]oct-2-ene 5 is shown to be useful in the synthesis of functi...
(bicyclo[3.2.1]oct-2-en-3-yl)trimethylsilane (3-trimethylsilylbicyclo[3.2.1]oct-2-ene) is ...
A wide range of exo-cis-bicyclo3.3.0-2-octyl ketones are obtained by the reaction of 1-trimethylsily...
A wide range of exo-cis-bicyclo[3.3.0]-2-octyl ketones are obtained by the reaction of 1-trimethylsi...
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extr...
exo-cis-Bicyclo[3.3.0]-2-octyl ketones I [R = Me, Et, Pr, CHMe2, (CH2)10Me, Ph, CH2Ph, CH:CHPh...
Several members of two new classes of bicyclic organosilicons, 3-silabicyclo{3.2.1}octanes (3-SBO) a...
A general method for the formation of acetals using chlorotrimethylsilane has been developed. Dioxol...
Several members of two new classes of bicyclic organosilicons, 3-silabicyclo[3.2.1]octanes (3-SBO) a...
Trimethylsilyl enol ethers of 1,3-diketones are generated “in situ†or obtained in high iso...
The preparation of the titte compounds is reported starting from the corresponding bromo derivatives...
The 5,6,9,10-tetrahydro-7,8-benzocyclooctenedione 4 has been synthesized through fragmentation of a ...
1,1-Bis(trimethylsilyloxy)ketene acetals represent useful synthetic building blocks which can be reg...
The reactions of bis (trimethylsilyl) peroxide with alkyl, vinyl, alkynyl, aromatic and heteroaromat...
Bicyclo[1.1.1]pentanes have emerged as bioisosteres, used by medicinal chemists to replace 1,4-disub...