THE REACTION OF TETRAMETHYLSILANE WITH BORON TRIBROMIDE
- Lewkowski, Jarosław
- Vaultier, Michel
Publication date
December 2001
DOI Publisher
Walter de Gruyter (Previously published by Freund Publishing House Ltd.) ISSN
2191-0219 Journal
Main Group Metal Chemistry Language
EnglishAbstract
The reaction of tetramethylsilane with boron tribromide in deuterochloroform in ambient temperature or at 40°C led to bromotrimethylsilane (3) and to dibromomethylborane (4). Identity of products was confirmed by NMR spectroscopy. Analogical reaction carried out in 1,3-dichloropropane allowed to separate products of the reaction and to obtain them in 68% and 59% yields respectively.CNRS Franc
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