Copper-Catalyzed Tandem Asymmetric Borylation of beta-Chloroalkyl Aryl Ketones and Related Compounds

Jiang, Quanbin
Guo, Tenglong
Yu, Zhengkun

Open link

Publication date

February 2015

DOI

10.1002/cctc.201402823

ISSN

1867-3880

Citation count (estimate)

Abstract

The Cu-catalyzed, one-pot tandem (asymmetric) borylation of -chloroalkyl aryl ketones via the insitu generated acyclic enones with bis(pinacolato)diboron was achieved efficiently to reach up to 97% yield and 99% enantioselectivity for the formal sp(3) CCl borylation products. The present methodology provides an efficient alternative route to (chiral) alkylboron compounds

Extracted data

We use cookies to provide a better user experience.

Data Protection

Copper-Catalyzed Tandem Asymmetric Borylation of beta-Chloroalkyl Aryl Ketones and Related Compounds

Abstract

Extracted data

Copper-Catalyzed Tandem Asymmetric Borylation of beta-Chloroalkyl Aryl Ketones and Related Compounds

Abstract

Extracted data

Related items

Related items