Add to ORKGA highly regio- and enantioselective rhodium-catalyzed 1,4-addition of arylboronic acids to beta,gamma-unsaturated alpha-ketoamides using a simple new chiral sulfinylphosphine ligand is described. This transformation provides an attractive approach to construct chiral nonracemic gamma,gamma-diarylsubstituted carbonyl compounds, as exemplified in the concise syntheses of sertraline and tetrahydroquinoline-2-carboxylamide
Rhodium complexes based upon chiral sulfinamide-alkene, TADDOL-derived phosphoramidite, or diene lig...
A chiral bicyclic bridgehead phosphoramidite (briphos) prepared from 1-aminoindane is a highly effic...
A simple catalyst system of Rh(I)/sulfur-olefin with exceptional catalytic performance has been dev...
Rh-Catalyzed asymmetric 1,4-selective addition of arylboronic acids to beta,gamma-unsaturated alpha-...
A site-selective rhodium-catalyzed asymmetric 1,4-/1,2-addition of arylboronic acids to challenging ...
The enantioselective rhodium-catalyzed 1,2-addition of arylboronates to cyclic <i>N</i>-sulfamidate ...
A step-wise reductive method that converts nonracemic gamma-chiral alpha-ketoamides into amide deriv...
Rhodium complexes based upon chiral sulfinamide–alkene, TADDOL-derived phosphoramidite, or diene lig...
A general method to obtain enantioenriched 1,3,3-triarylpropan-1-ones bearing a diarylmethine stereo...
A method for the enantioselective synthesis of chiral α-tertiary amines via Rh-catalyzed 1,2-additio...
International audienceIn 1998, Hayashi and Miyaura reported the first asymmetric conjugate addition ...
A series of chiral beta-aryl-gamma-amino acid ester derivatives were synthesized in high enantiosele...
Efficient Rh-catalyzed asymmetric 1,4-addition of arylboronic acids to ethyl-gamma-phthalimidocroton...
Phosphoramidites are effective chiral ligands in the rhodium catalyzed addition of arylboronic acids...
Rhodium-catalyzed asymmetric 1,4-addition of arylboronic acids to beta-phthaliminoacrylate esters to...
Rhodium complexes based upon chiral sulfinamide-alkene, TADDOL-derived phosphoramidite, or diene lig...
A chiral bicyclic bridgehead phosphoramidite (briphos) prepared from 1-aminoindane is a highly effic...
A simple catalyst system of Rh(I)/sulfur-olefin with exceptional catalytic performance has been dev...
Rh-Catalyzed asymmetric 1,4-selective addition of arylboronic acids to beta,gamma-unsaturated alpha-...
A site-selective rhodium-catalyzed asymmetric 1,4-/1,2-addition of arylboronic acids to challenging ...
The enantioselective rhodium-catalyzed 1,2-addition of arylboronates to cyclic <i>N</i>-sulfamidate ...
A step-wise reductive method that converts nonracemic gamma-chiral alpha-ketoamides into amide deriv...
Rhodium complexes based upon chiral sulfinamide–alkene, TADDOL-derived phosphoramidite, or diene lig...
A general method to obtain enantioenriched 1,3,3-triarylpropan-1-ones bearing a diarylmethine stereo...
A method for the enantioselective synthesis of chiral α-tertiary amines via Rh-catalyzed 1,2-additio...
International audienceIn 1998, Hayashi and Miyaura reported the first asymmetric conjugate addition ...
A series of chiral beta-aryl-gamma-amino acid ester derivatives were synthesized in high enantiosele...
Efficient Rh-catalyzed asymmetric 1,4-addition of arylboronic acids to ethyl-gamma-phthalimidocroton...
Phosphoramidites are effective chiral ligands in the rhodium catalyzed addition of arylboronic acids...
Rhodium-catalyzed asymmetric 1,4-addition of arylboronic acids to beta-phthaliminoacrylate esters to...
Rhodium complexes based upon chiral sulfinamide-alkene, TADDOL-derived phosphoramidite, or diene lig...
A chiral bicyclic bridgehead phosphoramidite (briphos) prepared from 1-aminoindane is a highly effic...
A simple catalyst system of Rh(I)/sulfur-olefin with exceptional catalytic performance has been dev...