Modeling and control of air stream and hydrogen flow with recirculation in a PEM fuel cell system - I. Control-oriented modeling

Transient behavior is one of the key requirements for the vehicular application of proton exchange membrane (PEM) fuel cell. The goal of this study is to develop a dynamic model of PEM fuel cell system (FCS) that is capable of characterizing the mixed effects of gas flow, pressure and humidity. In addition to the model of air supply system, the anode recirculation is also presented in this paper by an analytical model of injection pump. A steady-state, isothermal analytical fuel cell model is adopted to analyze the mass transfer in the diffusion layer and water transportation in the membrane. The liquid water accumulation in the cathode flow channel is described by a finite-rate phase-change model and the cathode flooding in the diffusion layer is also discussed. The transient phenomena in FCS are captured by the mechanical inertia of compressor and flow filling in lumped-parameter volumes of manifolds, anode and cathode. (c) 2006 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved