Dicarbonylsalicylaldoximatorhodium (Rh(sox)(CO)(2)) combined with phosphorous ligands exhibits high activity for hydroformylation of olefins under mild conditions. The reaction rate and regioselectivity strongly depend on the phosphorous ligands and substrate. In the case of styrene, the branched aldehyde is the major product, almost pure 2-phenylpropanal can be afforded at 1.0 MPa. In the case of 1-hexene, n-aldehyde is predominant over iso-aldehyde. Diphosphine ligands are much more active than monophosphine ligands, but the latter give higher regioselectivity for n-aldehyde. Increasing the CO/H-2 ratio results in a decrease of reaction rate and the regioselectivity towards n-aldehyde, probably due to the formation of more hydridic LnRhH....
We report SUPRAphos-based rhodium catalysts that are unusually regioselective in the hydroformylatio...
The organic triphenyl-phosphine ligand was directly used to modify the Rh/SiO2 catalyst to prepare P...
We thank the Eastman Chemical Company for funding of RCH, EPSRC for funding of PD (EP003868/1).The p...
Hydroformylation of vinylarenes, alkenes and cyclic olefins has been investigated using (1,5-cyclooc...
The hydroformylation of cyclohexene, 1-pentene and styrene under mild conditions (25-50 \ub0C, 1 atm...
Usually the Rh-catalyzed hydroformylation of styrene predominantly yields the branched, chiral aldeh...
Usually the Rh-catalyzed hydroformylation of styrene predominantly yields the branched, chiral aldeh...
Usually the Rh-catalyzed hydroformylation of styrene predominantly yields the branched, chiral aldeh...
In Chapter 1, a general introduction to the reaction of rhodium-catalyzed hydroformylation of olefin...
Usually the Rh-catalyzed hydroformylation of styrene predominantly yields the branched, chiral aldeh...
The hydroformylation of olefins over rhodium catalysts, with phosphorus ligands added in situ, has b...
This paper reports experimental and computational studies on the mechanism of a rhodium-catalysed hy...
Usually the Rh-catalyzed hydroformylation of styrene predominantly yields the branched, chiral aldeh...
Usually the Rh-catalyzed hydroformylation of styrene predominantly yields the branched, chiral aldeh...
The paper describes the composition of the resting states of several catalysts for alkene hydroformy...
We report SUPRAphos-based rhodium catalysts that are unusually regioselective in the hydroformylatio...
The organic triphenyl-phosphine ligand was directly used to modify the Rh/SiO2 catalyst to prepare P...
We thank the Eastman Chemical Company for funding of RCH, EPSRC for funding of PD (EP003868/1).The p...
Hydroformylation of vinylarenes, alkenes and cyclic olefins has been investigated using (1,5-cyclooc...
The hydroformylation of cyclohexene, 1-pentene and styrene under mild conditions (25-50 \ub0C, 1 atm...
Usually the Rh-catalyzed hydroformylation of styrene predominantly yields the branched, chiral aldeh...
Usually the Rh-catalyzed hydroformylation of styrene predominantly yields the branched, chiral aldeh...
Usually the Rh-catalyzed hydroformylation of styrene predominantly yields the branched, chiral aldeh...
In Chapter 1, a general introduction to the reaction of rhodium-catalyzed hydroformylation of olefin...
Usually the Rh-catalyzed hydroformylation of styrene predominantly yields the branched, chiral aldeh...
The hydroformylation of olefins over rhodium catalysts, with phosphorus ligands added in situ, has b...
This paper reports experimental and computational studies on the mechanism of a rhodium-catalysed hy...
Usually the Rh-catalyzed hydroformylation of styrene predominantly yields the branched, chiral aldeh...
Usually the Rh-catalyzed hydroformylation of styrene predominantly yields the branched, chiral aldeh...
The paper describes the composition of the resting states of several catalysts for alkene hydroformy...
We report SUPRAphos-based rhodium catalysts that are unusually regioselective in the hydroformylatio...
The organic triphenyl-phosphine ligand was directly used to modify the Rh/SiO2 catalyst to prepare P...
We thank the Eastman Chemical Company for funding of RCH, EPSRC for funding of PD (EP003868/1).The p...