A practical method has been developed for the C-sulfinylation of enamides and enecarbamates using sodium phenylsulfinate/methyltrichlorosilane (PhSO2Na/MeSiCl3) as the sulfinylating reagent and N,N-dimethylacetamide (DMAc) as the Lewis base promoter. which allows for the preparation of a variety of N-protected-beta-sulfinylenamines in high yields and good stereoselectivities. The Lewis base is found to be important for both the in situ generation of the active sulfinylating species (PhSOCl) and the sulfinylation step
The indium-promoted allylation of enantiomerically pure N-tert-butylsulfinyl imines has been shown t...
In this thesis, novel methods for the synthesis of sulfondiimines and sulfondiimidamides are describ...
In the following thesis, new methodologies which exploit sulfinylamine reagents to enable one-pot sy...
© 2014 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. An improved method for the tert-butanesulfinylati...
A new N-silyl sulfinylamine reagent allows the rapid preparation of a broad range of (hetero)aryl, a...
The syntheses of different enantiomerically N-acyl N-alkyl p-toluenesulfinamides 5, by N-sulfinylati...
By employing Senanayake's oxathiazolidine-2-oxide reagent, a collection of sulfinamides was prepared...
N-Sulfinylimino esters are a highly versatile class of compounds, they are already widely used with...
Sulfinamides have widespread applications in organic synthesis, especially for the preparation of S(...
In this work we report a new synthetic tactic for the straightforward preparation of hardly accessib...
Sulfinimines are important chiral auxiliaries for asymmetric synthesis of amines. Enantiopure sulfin...
A facile and efficient method was developed for the preparation of a variety of aryl, heteroaryl, an...
ABSTRACT: A catalytic, enantioselective, Lewis base-catalyzed α-sulfenylation of silyl enol ethers h...
In this work we investigated, for the first time, the reactivity of sulfinimidate esters as an elect...
Metal- and additive-free transsulfinamidation of N-unsubstituted sulfinamides and N-pivaloyl-protect...
The indium-promoted allylation of enantiomerically pure N-tert-butylsulfinyl imines has been shown t...
In this thesis, novel methods for the synthesis of sulfondiimines and sulfondiimidamides are describ...
In the following thesis, new methodologies which exploit sulfinylamine reagents to enable one-pot sy...
© 2014 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. An improved method for the tert-butanesulfinylati...
A new N-silyl sulfinylamine reagent allows the rapid preparation of a broad range of (hetero)aryl, a...
The syntheses of different enantiomerically N-acyl N-alkyl p-toluenesulfinamides 5, by N-sulfinylati...
By employing Senanayake's oxathiazolidine-2-oxide reagent, a collection of sulfinamides was prepared...
N-Sulfinylimino esters are a highly versatile class of compounds, they are already widely used with...
Sulfinamides have widespread applications in organic synthesis, especially for the preparation of S(...
In this work we report a new synthetic tactic for the straightforward preparation of hardly accessib...
Sulfinimines are important chiral auxiliaries for asymmetric synthesis of amines. Enantiopure sulfin...
A facile and efficient method was developed for the preparation of a variety of aryl, heteroaryl, an...
ABSTRACT: A catalytic, enantioselective, Lewis base-catalyzed α-sulfenylation of silyl enol ethers h...
In this work we investigated, for the first time, the reactivity of sulfinimidate esters as an elect...
Metal- and additive-free transsulfinamidation of N-unsubstituted sulfinamides and N-pivaloyl-protect...
The indium-promoted allylation of enantiomerically pure N-tert-butylsulfinyl imines has been shown t...
In this thesis, novel methods for the synthesis of sulfondiimines and sulfondiimidamides are describ...
In the following thesis, new methodologies which exploit sulfinylamine reagents to enable one-pot sy...