Three-Coordinate Terminal Imidoiron(III) Complexes: Structure, Spectroscopy, and Mechanism of Formation

Investigations of Iron–Nitrogen Bonding at Synthetic Iron–Sulfur Clusters

Sridharan, Arun

June 2022

The coordination chemistry of nitrogenous ligands at high-spin iron is investigated through the synt...

New tricyanoiron(III) building blocks for the construction of molecule-based magnets

Wong, WT
Lau, TC
Xiang, J
Lau, PH
Man, WL
Gao, S

January 2010

A series of tricyanoiron(III) complexes with the general formula mer-[Fe III(5-Xsap)(CN) 3] 2- (X = ...

Stepwise Reduction of Dinitrogen Bond Order by a Low-Coordinate Iron Complex

Smith, Jeremy M.
Lachicotte, Rene J.
Pittard, Karl A.
Cundari, Thomas R., 1964-
Lukat-Rodgers, Gudrun
Rodgers, Kenton R.
Holland, Patrick L.

August 2001

This article discusses stepwise reduction of dinitrogen bond order by a low-coordinate iron complex

Three-coordinate terminal imidoiron(III) complexes: Structure, spectroscopy, and mechanism of formation

Cowley, Ryan E.
Deyonker, Nathan J.
Eckert, Nathan A.
Cundari, Thomas R.
Debeer, Serena
Bill, Eckhard
Ottenwaelder, Xavier
Flaschenriem, Christine

July 2010

Reaction of 1-adamantyl azide with iron(I) diketiminate precursors gives metastable but isolable imi...

Three-coordinate terminal imidoiron(III) complexes: Structure, spectroscopy, and mechanism of formation

Cowley, Ryan E.
Deyonker, Nathan J.
Eckert, Nathan A.
Cundari, Thomas R.
Debeer, Serena
Bill, Eckhard
Ottenwaelder, Xavier
Flaschenriem, Christine

July 2010

Reaction of 1-adamantyl azide with iron(I) diketiminate precursors gives metastable but isolable imi...

Three-Coordinate Terminal Imidoiron(III) Complexes: Structure, Spectroscopy, and Mechanism of Formation

Ryan E. Cowley
Nathan J. Deyonker
Nathan A. Eckert
Thomas R. Cundari
Eckhard Bill
Xavier Ottenwaelder
Christine Flaschenriem
Patrick L

October 2015

Reaction of 1-adamantyl azide with iron(I) diketiminate precursors gives metastable but isolable imi...

Electronically Unsaturated Three-Coordinate Chloride and Methyl Complexes of Iron, Cobalt, and Nickel

Holland, Patrick L.
Cundari, Thomas R., 1964-
Perez, Lanyn L.
Eckert, Nathan A.
Lachicotte, Rene J.

November 2002

This article discusses electronically unsaturated three-coordinate chloride and methyl complexes of ...

Bis(tricarbonyliron)‐para‐quinodimethanes: preparation and molecular structure

Koray, A.
Krieger, C.
Staab, H.

June 1985

The stabilization of p‐quinodimethanes can be achieved by complexation. According to an X‐ray struct...

Synthesis and properties of FeIII and CoIII complexes: structures of [(L2)Fe(N3)3], [(L2)2Fe2(μ-O)(μ-O2CMe)2][ClO4]2·2H2O and [(L2)2Co2(μ-OH)2(μ-O2CMe)][ClO4]3·MeCN [L2= methyl[2-(2-pyridyl)ethyl](2-pyridylmethyl)amine]

Mukherjee, Jhumpa
Balamurugan, V.
Gupta, Rajeev
Mukherjee, Rabindra Nath

January 2003

Three mononuclear half-sandwich iron(III) (S =½) complexes [(L2/L3)FeCl3]·H2O (½) and...

Synthesis and Redox Properties of Triiron Complexes Featuring Strong Fe-Fe Interactions

Zhao, Qinliang
Betley, Theodore A

January 2011

A modular hexadentate polyamide ligand directs the assembly of triiron complexes (see structure). Cr...

Three-Coordinate Cobalt(IV) and Cobalt(V) Imido Complexes with N‑Heterocyclic Carbene Ligation: Synthesis, Structure, and Their Distinct Reactivity in C–H Bond Amination

Long Zhang (315279)
Yuesheng Liu (1438930)
Liang Deng (553510)

November 2014

The reaction of the cobalt(0) alkene complex [(IMes)Co(η2:η2-dvtms)] (1</...

Methane Activation by Group IVB Imido Complexes

Cundari, Thomas R., 1964-

January 1992

Article discussing an ab initio study of methane activation by group IVB imido complexes

A Masked Two-Coordinate Cobalt (I) Complex That Activates C-F Bonds

Dugan, Thomas R.
Sun, Xianru
Rybak-Akimova, Elena V.
Olatunji-Ojo, Olayinka
Cundari, Thomas R., 1964-
Holland, Patrick L.

July 2011

This article discusses a masked two-coordinate cobalt(I) complex that activates C-F bonds

Evaluating the Identity and Diiron Core Transformations of a (μ-Oxo)diiron(III) Complex Supported by Electron-Rich Tris(pyridyl-2-methyl)amine Ligands

Loi H. Do (1334136)
Genqiang Xue (1852684)
Lawrence Que (1312980)
Stephen J. Lippard (1233759)

February 2012

The composition of a (μ-oxo)diiron(III) complex coordinated by tris[(3,5-dimethyl-4-methoxy)pyri...

Reversible Beta-Hydrogen Elimination of Three-Coordinate Iron(II) Alkyl Complexes: Mechanistic and Thermodynamic Studies

Vela, Javier
Vaddadi, Sridhar
Cundari, Thomas R., 1964-
Smith, Jeremy M.
Gregory, Elizabeth A.
Lachicotte, Rene J.
Flaschenriem, Christine J.
Holland, Patrick L.

October 2004

Article discussing mechanistic and thermodynamic studies and reversible beta-hydrogen elimination of...

Investigations of Iron–Nitrogen Bonding at Synthetic Iron–Sulfur Clusters

Sridharan, Arun

June 2022

The coordination chemistry of nitrogenous ligands at high-spin iron is investigated through the synt...

New tricyanoiron(III) building blocks for the construction of molecule-based magnets

Wong, WT
Lau, TC
Xiang, J
Lau, PH
Man, WL
Gao, S

January 2010

A series of tricyanoiron(III) complexes with the general formula mer-[Fe III(5-Xsap)(CN) 3] 2- (X = ...

Stepwise Reduction of Dinitrogen Bond Order by a Low-Coordinate Iron Complex

Smith, Jeremy M.
Lachicotte, Rene J.
Pittard, Karl A.
Cundari, Thomas R., 1964-
Lukat-Rodgers, Gudrun
Rodgers, Kenton R.
Holland, Patrick L.

August 2001

This article discusses stepwise reduction of dinitrogen bond order by a low-coordinate iron complex

Three-coordinate terminal imidoiron(III) complexes: Structure, spectroscopy, and mechanism of formation

Cowley, Ryan E.
Deyonker, Nathan J.
Eckert, Nathan A.
Cundari, Thomas R.
Debeer, Serena
Bill, Eckhard
Ottenwaelder, Xavier
Flaschenriem, Christine

July 2010

Reaction of 1-adamantyl azide with iron(I) diketiminate precursors gives metastable but isolable imi...

Three-coordinate terminal imidoiron(III) complexes: Structure, spectroscopy, and mechanism of formation

Cowley, Ryan E.
Deyonker, Nathan J.
Eckert, Nathan A.
Cundari, Thomas R.
Debeer, Serena
Bill, Eckhard
Ottenwaelder, Xavier
Flaschenriem, Christine

July 2010

Reaction of 1-adamantyl azide with iron(I) diketiminate precursors gives metastable but isolable imi...

Three-Coordinate Terminal Imidoiron(III) Complexes: Structure, Spectroscopy, and Mechanism of Formation

Ryan E. Cowley
Nathan J. Deyonker
Nathan A. Eckert
Thomas R. Cundari
Eckhard Bill
Xavier Ottenwaelder
Christine Flaschenriem
Patrick L

October 2015

Reaction of 1-adamantyl azide with iron(I) diketiminate precursors gives metastable but isolable imi...

Electronically Unsaturated Three-Coordinate Chloride and Methyl Complexes of Iron, Cobalt, and Nickel

Holland, Patrick L.
Cundari, Thomas R., 1964-
Perez, Lanyn L.
Eckert, Nathan A.
Lachicotte, Rene J.

November 2002

This article discusses electronically unsaturated three-coordinate chloride and methyl complexes of ...

Bis(tricarbonyliron)‐para‐quinodimethanes: preparation and molecular structure

Koray, A.
Krieger, C.
Staab, H.

June 1985

The stabilization of p‐quinodimethanes can be achieved by complexation. According to an X‐ray struct...

Synthesis and properties of FeIII and CoIII complexes: structures of [(L2)Fe(N3)3], [(L2)2Fe2(μ-O)(μ-O2CMe)2][ClO4]2·2H2O and [(L2)2Co2(μ-OH)2(μ-O2CMe)][ClO4]3·MeCN [L2= methyl[2-(2-pyridyl)ethyl](2-pyridylmethyl)amine]

Mukherjee, Jhumpa
Balamurugan, V.
Gupta, Rajeev
Mukherjee, Rabindra Nath

January 2003

Three mononuclear half-sandwich iron(III) (S =½) complexes [(L2/L3)FeCl3]·H2O (½) and...

Synthesis and Redox Properties of Triiron Complexes Featuring Strong Fe-Fe Interactions

Zhao, Qinliang
Betley, Theodore A

January 2011

A modular hexadentate polyamide ligand directs the assembly of triiron complexes (see structure). Cr...

Three-Coordinate Cobalt(IV) and Cobalt(V) Imido Complexes with N‑Heterocyclic Carbene Ligation: Synthesis, Structure, and Their Distinct Reactivity in C–H Bond Amination

Long Zhang (315279)
Yuesheng Liu (1438930)
Liang Deng (553510)

November 2014

The reaction of the cobalt(0) alkene complex [(IMes)Co(η2:η2-dvtms)] (1</...

Methane Activation by Group IVB Imido Complexes

Cundari, Thomas R., 1964-

January 1992

Article discussing an ab initio study of methane activation by group IVB imido complexes

A Masked Two-Coordinate Cobalt (I) Complex That Activates C-F Bonds

Dugan, Thomas R.
Sun, Xianru
Rybak-Akimova, Elena V.
Olatunji-Ojo, Olayinka
Cundari, Thomas R., 1964-
Holland, Patrick L.

July 2011

This article discusses a masked two-coordinate cobalt(I) complex that activates C-F bonds

Evaluating the Identity and Diiron Core Transformations of a (μ-Oxo)diiron(III) Complex Supported by Electron-Rich Tris(pyridyl-2-methyl)amine Ligands

Loi H. Do (1334136)
Genqiang Xue (1852684)
Lawrence Que (1312980)
Stephen J. Lippard (1233759)

February 2012

The composition of a (μ-oxo)diiron(III) complex coordinated by tris[(3,5-dimethyl-4-methoxy)pyri...

Reversible Beta-Hydrogen Elimination of Three-Coordinate Iron(II) Alkyl Complexes: Mechanistic and Thermodynamic Studies

Vela, Javier
Vaddadi, Sridhar
Cundari, Thomas R., 1964-
Smith, Jeremy M.
Gregory, Elizabeth A.
Lachicotte, Rene J.
Flaschenriem, Christine J.
Holland, Patrick L.

October 2004

Article discussing mechanistic and thermodynamic studies and reversible beta-hydrogen elimination of...

Investigations of Iron–Nitrogen Bonding at Synthetic Iron–Sulfur Clusters

Sridharan, Arun

June 2022

The coordination chemistry of nitrogenous ligands at high-spin iron is investigated through the synt...

New tricyanoiron(III) building blocks for the construction of molecule-based magnets

Wong, WT
Lau, TC
Xiang, J
Lau, PH
Man, WL
Gao, S

January 2010

A series of tricyanoiron(III) complexes with the general formula mer-[Fe III(5-Xsap)(CN) 3] 2- (X = ...

Stepwise Reduction of Dinitrogen Bond Order by a Low-Coordinate Iron Complex

Smith, Jeremy M.
Lachicotte, Rene J.
Pittard, Karl A.
Cundari, Thomas R., 1964-
Lukat-Rodgers, Gudrun
Rodgers, Kenton R.
Holland, Patrick L.

August 2001

This article discusses stepwise reduction of dinitrogen bond order by a low-coordinate iron complex

Three-Coordinate Terminal Imidoiron(III) Complexes: Structure, Spectroscopy, and Mechanism of Formation

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Three-Coordinate Terminal Imidoiron(III) Complexes: Structure, Spectroscopy, and Mechanism of Formation

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