Novel trinuclear Ni(II) complex [Ni<sub>3</sub>(pmdien)<sub>3</sub>(btc)(H<sub>2</sub>O)<sub>3</sub>](ClO<sub>4</sub>)<sub>3</sub>·4H<sub>2</sub>O, <b>1</b> where pmdien = N,N,N′,N′,N″-pentamethyldiethylenetriamine, H<sub>3</sub>btc = 1,3,5-benzenetricarboxylic (trimesic) acid, has been prepared and structurally characterized. Three nickel atoms are bridged by btc trianion and their coordination sphere is completed by three N atoms of pmdien and O atom of the water molecule. The three nickel(II) magnetic centers are equivalent and their coordination spheres are completed to deformed octahedrons. Magnetic susceptibility was measured over the temperature range 1.8–300 K and zJ′ = −0.19 cm<sup>−1</sup>, D = 3.79 cm<sup>−1</sup>, g = 2.18 param...
Research on structure and magnetic properties of polynuclear metal complexes to understand the struc...
Three new Ni(II) complexes, [NiL(NO2)(H2O)] (1), [Ni2L2(PhCH2COO)2(H2O)] (2) and [Ni2L2(N(CN)2)2(H2O...
International audiencemu-Benzene-1,2,4,5-tetracarboxylato-kappa O-2(1)O-4)bis-[aqua-bis-2-(aminometh...
Novel trinuclear Ni(II) complex [Ni3(pmdien)3(btc)(H2O)3](ClO4)3\ub74H2O, 1 where pmdien = N,N,N′,N′...
A novel trinuclear nickel(II) complex with N,N,N',N'',N''-pentamethyldiethylenetriamine (pmdien) and...
Three new trinuclear nickel (II) complexes with the general composition [Ni<sub>3</sub>L<sub>3</sub>...
A diphenoxido bridged dinuclear Ni(II) complex [Ni2L2 (NO2)2] (1) and a μ2 and μ3-phenoxid...
Employing N-benzoyl-salicylhydrazide (H 3bzshz) and imidazole (Himdz) as mixed ligands, a novel line...
A new linear trinuclear nickel (II) complex, [Ni<sub>3</sub>L<sub>2</sub>(OCn)<sub>4</sub>] (HL = 2-...
A new binuclear nickel(II) complex [Ni2L2(N3)2](ClO4)2 1 has been synthesized and characterized. The...
Three new linear trinuclear nickel(II) complexes, [Ni-3(salpen)(2)(OAc)(2)(H2O)(2)]center dot 4H(2)O...
The magnetic properties of Ni 3(TFDAA) 2(OH) 2(H 2O) 6 (TFDAA = 1,1,1-trifluoro-2,4,6-heptanetrionat...
Three new linear trinuclear nickel (II) complexes, [Ni<sub>3</sub>(salpen)<sub>2</sub>(OAc)<sub>2</s...
International audienceTriple stranded NiII2-metallacyclic complexes Na2.5[Ni2(bpcb)3]·0.5OH·18.5H2O ...
Three nickel(II) complexes [Ni2(μ-trien)(trien)2](ClO4)4 (1), {[Ni2(μ-tren)2(tren)](ClO4)4·3,25H2O}n...
Research on structure and magnetic properties of polynuclear metal complexes to understand the struc...
Three new Ni(II) complexes, [NiL(NO2)(H2O)] (1), [Ni2L2(PhCH2COO)2(H2O)] (2) and [Ni2L2(N(CN)2)2(H2O...
International audiencemu-Benzene-1,2,4,5-tetracarboxylato-kappa O-2(1)O-4)bis-[aqua-bis-2-(aminometh...
Novel trinuclear Ni(II) complex [Ni3(pmdien)3(btc)(H2O)3](ClO4)3\ub74H2O, 1 where pmdien = N,N,N′,N′...
A novel trinuclear nickel(II) complex with N,N,N',N'',N''-pentamethyldiethylenetriamine (pmdien) and...
Three new trinuclear nickel (II) complexes with the general composition [Ni<sub>3</sub>L<sub>3</sub>...
A diphenoxido bridged dinuclear Ni(II) complex [Ni2L2 (NO2)2] (1) and a μ2 and μ3-phenoxid...
Employing N-benzoyl-salicylhydrazide (H 3bzshz) and imidazole (Himdz) as mixed ligands, a novel line...
A new linear trinuclear nickel (II) complex, [Ni<sub>3</sub>L<sub>2</sub>(OCn)<sub>4</sub>] (HL = 2-...
A new binuclear nickel(II) complex [Ni2L2(N3)2](ClO4)2 1 has been synthesized and characterized. The...
Three new linear trinuclear nickel(II) complexes, [Ni-3(salpen)(2)(OAc)(2)(H2O)(2)]center dot 4H(2)O...
The magnetic properties of Ni 3(TFDAA) 2(OH) 2(H 2O) 6 (TFDAA = 1,1,1-trifluoro-2,4,6-heptanetrionat...
Three new linear trinuclear nickel (II) complexes, [Ni<sub>3</sub>(salpen)<sub>2</sub>(OAc)<sub>2</s...
International audienceTriple stranded NiII2-metallacyclic complexes Na2.5[Ni2(bpcb)3]·0.5OH·18.5H2O ...
Three nickel(II) complexes [Ni2(μ-trien)(trien)2](ClO4)4 (1), {[Ni2(μ-tren)2(tren)](ClO4)4·3,25H2O}n...
Research on structure and magnetic properties of polynuclear metal complexes to understand the struc...
Three new Ni(II) complexes, [NiL(NO2)(H2O)] (1), [Ni2L2(PhCH2COO)2(H2O)] (2) and [Ni2L2(N(CN)2)2(H2O...
International audiencemu-Benzene-1,2,4,5-tetracarboxylato-kappa O-2(1)O-4)bis-[aqua-bis-2-(aminometh...