A verification of the photolytic decomposition pathways of 3-tert-butyl-3-chlorodiazirine based on the application of the C-60 probe technique

C-60 acts as a mechanistic probe for the formation of carbene and for the rearranged product via the excited state in the photolysis of 3-t-butyl-3-chlorodiazirine. (C) 2004 Published by Elsevier Ltd.PT: J; CR: AKASAKA T, 2000, J AM CHEM SOC, V122, P7134 BONNEAU R, 2000, J PHYS CHEM A, V104, P4115 DIEDERICH F, 1994, CHEM SOC REV, V1, P243 GRAHAM WH, 1965, J AM CHEM SOC, V87, P4396 HIRSH A, 1999, FULLERENES RELATED S KORSHUNOVA GA, 2000, MOL BIOL+, V34, P823 LIU MTH, 1996, J AM CHEM SOC, V118, P8098 MODARELLI DA, 1992, J AM CHEM SOC, V114, P7034 MODARELLI DA, 1993, J AM CHEM SOC, V115, P470 MOSS RA, 1990, J AM CHEM SOC, V112, P5642 MOSS RA, 1993, J CHEM SOC CHEM COMM, P1597 RICHARDS FM, 2000, PROTEIN SCI, V9, P2506 WAKAHARA T, 2002, J AM CHEM SOC, V124, P9465 WHITE WR, 1992, J ORG CHEM, V57, P2841; NR: 14; TC: 2; J9: TETRAHEDRON LETT; PG: 2; GA: 843UMSource type: Electronic(1