Nucleophilic substitution reactions of the (η6-o-, -m-, or -p-chloronitrobenzene)(η5-cyclopentadienyl)iron cation (2a, 2b, or 2c, respectively) with aniline, n-butylamine, or pyrrolidine as nucleophile were investigated. It was found that only selective displacement of the nitro group occurred for reactions with aniline. For reaction with n-butylamine or pyrrolidine, o-isomer 2a resulted in the selective displacement of only the chloro group, giving rise to the (η6-o-n-butylaminonitrobenzene)(η5-cyclo-pentadienyl)iron cation (5a) or the (η6-o-nitro-N-pyrrolidinylbenzene)(η5-cyclopentadienyl)iron cation (7a), respectively. With the m- or p-isomer 2b or 2c, reaction with n-butylamine or pyrrolidine gave a mixture of substitution products from...
Efficient catalysis is provided by ferrous chloride in the nucleophilic aromatic substitution reacti...
The kinetics of the nucleophilic aromatic substitution of some 2-L-5-nitrothiophenes (para-like isom...
This study investigates the reactivity of the electrophilic nitroso group towards nucleophilic anili...
Nucleophilic substitution reactions with the cyclopentadienyliron (CpFe) complex of m- or p-dichloro...
abstract: Reaction of [(η6-o-Cl2C6H4)Fe(η5-C5H5)][PF6] (I) with an excess of PhOH or p-MeC6H4SH in...
Reaction of the cyclopentadienyliron (CpFe) complex e.g. I-III with an excess of BuNH2 gave only mon...
n6-Chloroarene or nitroarene-n5-cyclopentadienyliron hexafluorophosphates react readily with CF3CH2O...
Reaction of η6-o-dichlorobenzene-η5-cyclopentadienyliron hexafluorophosphate (IPF6) with an excess o...
Quantitative kinetic studies have be en made of reactions of the (eta(6)-chlorobenzene)(eta(5)-cyclo...
A unique synthetic route to cyclopentadienyliron complexes of functionalized nitrobenzene has been d...
Degradation of chlorobenzene, dichlorobenzenes and chloronitrobenzenes (ClB, x-Cl2B and x-ClNO2B) wa...
3-[Tricarbonyl(eta(6)-4-toluene)chromium]indene (4) was obtained as the only separated product from ...
The reaction rates for the nucleophilic aromatic substitution of 4,6-dichloro-5-nitrobenzofuroxan 1 ...
A unique route to the synthesis of 2-alkyl-2-arylphenylsulfonylacetonitriles via the nucleophilic ar...
The reactions of 1,2-dimethyl-, 1-phenyl-2-methyl-, 1,4-dimethyl-, and 1-phenyl-4-methyl- substitute...
Efficient catalysis is provided by ferrous chloride in the nucleophilic aromatic substitution reacti...
The kinetics of the nucleophilic aromatic substitution of some 2-L-5-nitrothiophenes (para-like isom...
This study investigates the reactivity of the electrophilic nitroso group towards nucleophilic anili...
Nucleophilic substitution reactions with the cyclopentadienyliron (CpFe) complex of m- or p-dichloro...
abstract: Reaction of [(η6-o-Cl2C6H4)Fe(η5-C5H5)][PF6] (I) with an excess of PhOH or p-MeC6H4SH in...
Reaction of the cyclopentadienyliron (CpFe) complex e.g. I-III with an excess of BuNH2 gave only mon...
n6-Chloroarene or nitroarene-n5-cyclopentadienyliron hexafluorophosphates react readily with CF3CH2O...
Reaction of η6-o-dichlorobenzene-η5-cyclopentadienyliron hexafluorophosphate (IPF6) with an excess o...
Quantitative kinetic studies have be en made of reactions of the (eta(6)-chlorobenzene)(eta(5)-cyclo...
A unique synthetic route to cyclopentadienyliron complexes of functionalized nitrobenzene has been d...
Degradation of chlorobenzene, dichlorobenzenes and chloronitrobenzenes (ClB, x-Cl2B and x-ClNO2B) wa...
3-[Tricarbonyl(eta(6)-4-toluene)chromium]indene (4) was obtained as the only separated product from ...
The reaction rates for the nucleophilic aromatic substitution of 4,6-dichloro-5-nitrobenzofuroxan 1 ...
A unique route to the synthesis of 2-alkyl-2-arylphenylsulfonylacetonitriles via the nucleophilic ar...
The reactions of 1,2-dimethyl-, 1-phenyl-2-methyl-, 1,4-dimethyl-, and 1-phenyl-4-methyl- substitute...
Efficient catalysis is provided by ferrous chloride in the nucleophilic aromatic substitution reacti...
The kinetics of the nucleophilic aromatic substitution of some 2-L-5-nitrothiophenes (para-like isom...
This study investigates the reactivity of the electrophilic nitroso group towards nucleophilic anili...