First determination of an absolute rate constant for a 1, 2‐phenyl migration to a carbene

The first determination of a 1,2-phenyl shift in alpha,alpha-dimethylbenzylchlorocarbene was achieved by nanosecond laser flash photolysis, tau = 50 ns.PT: J; CR: BONNEAU R, 1989, J AM CHEM SOC, V111, P5973 EVANSECK JD, 1990, J PHYS CHEM-US, V94, P5518 GRAHAM WH, 1965, J AM CHEM SOC, V87, P4396 JACKSON JE, IN PRESS ADV CARBENE JONES M, 1973, CARBENES, V1, P267 LIU MTH, 1992, J AM CHEM SOC, V114, P3604 LIU MTH, 1992, J PHOTOCH PHOTOBIO A, V63, P115 LIU MTH, 1992, J PHYS ORG CHEM, V5, P285 MOSS RA, IN PRESS ADV CARBENE MOSS RA, 1990, J AM CHEM SOC, V112, P5642 MOSS RA, 1992, J AM CHEM SOC, V114, P959 SARGEANT PB, 1964, TETRAHEDRON LETT, P3957 SUGIYAMA MH, 1992, J AM CHEM SOC, V114, P996; NR: 13; TC: 6; J9: J PHYS ORG CHEM; PG: 3; GA: MQ787Source type: Electronic(1