A synthesis of the C9–C16 segment of ambruticin is described which relies on organoiron methodology to establish the 1,2,3-trisubstituted cyclopropane ring
The ring-opening process of cyclopropane derivatives is prominent in biological processes and synthe...
The racemic (6-cyclo-heptadienyl)Fe(CO)3+ cation ((±)-7), prepared from cyclooctatetraene, was treat...
A modular synthesis of enantioenriched polyfunctionalized cyclobutanes was developed that features a...
Addition of alkenyl Grignard reagents to (1-methoxycarbonylpentadienyl)iron(1+) cation generates the...
The cyclopropane containing betaine, rac-dysibetaine CPa, was prepared from (1-methoxycarbonylpentad...
A route to 1,2,3-trisubstituted cyclopropanes has been developed. The relative stereochemistry at th...
The dihydropyranyl segment common to ambruticin and jerangolid A was prepared in six steps (31.7% yi...
The cyclopropane moiety is found in a wide variety of the natural products, from small amino acid mo...
A stereoselective route to cis-2-(2′-carboxycyclopropyl)glycine has been developed. exo-Nucleophilic...
The C1-C8 tetrahydropyran and the C17-C24 dihdropyran segments of ambruticin were prepared from L-ar...
The cyclopropane moiety is found in a wide variety of the natural products, from small amino acid mo...
The reaction of tricarbonyl and (dicarbonyl)triphenylphosphine (1-methoxycarbonyl-pentadientyl)iron(...
The first chapter of this thesis focuses on the synthesis and reactivity of cyclopropane hemimalonat...
The addition of stabilized carbon nucleophiles to tricarbonyl(1-methoxycarbonylpentadienyl)iron(1+) ...
The first chapter of this thesis consists of two related projects that explore novel reactivity of d...
The ring-opening process of cyclopropane derivatives is prominent in biological processes and synthe...
The racemic (6-cyclo-heptadienyl)Fe(CO)3+ cation ((±)-7), prepared from cyclooctatetraene, was treat...
A modular synthesis of enantioenriched polyfunctionalized cyclobutanes was developed that features a...
Addition of alkenyl Grignard reagents to (1-methoxycarbonylpentadienyl)iron(1+) cation generates the...
The cyclopropane containing betaine, rac-dysibetaine CPa, was prepared from (1-methoxycarbonylpentad...
A route to 1,2,3-trisubstituted cyclopropanes has been developed. The relative stereochemistry at th...
The dihydropyranyl segment common to ambruticin and jerangolid A was prepared in six steps (31.7% yi...
The cyclopropane moiety is found in a wide variety of the natural products, from small amino acid mo...
A stereoselective route to cis-2-(2′-carboxycyclopropyl)glycine has been developed. exo-Nucleophilic...
The C1-C8 tetrahydropyran and the C17-C24 dihdropyran segments of ambruticin were prepared from L-ar...
The cyclopropane moiety is found in a wide variety of the natural products, from small amino acid mo...
The reaction of tricarbonyl and (dicarbonyl)triphenylphosphine (1-methoxycarbonyl-pentadientyl)iron(...
The first chapter of this thesis focuses on the synthesis and reactivity of cyclopropane hemimalonat...
The addition of stabilized carbon nucleophiles to tricarbonyl(1-methoxycarbonylpentadienyl)iron(1+) ...
The first chapter of this thesis consists of two related projects that explore novel reactivity of d...
The ring-opening process of cyclopropane derivatives is prominent in biological processes and synthe...
The racemic (6-cyclo-heptadienyl)Fe(CO)3+ cation ((±)-7), prepared from cyclooctatetraene, was treat...
A modular synthesis of enantioenriched polyfunctionalized cyclobutanes was developed that features a...