Add to ORKGThe pyrolysis of cis- and trans-2-methylcyclohexyl p-toluenesulfonates in the liquid phase at 180°gave methylcyclohexane (21 and 18%), 1-methylcyclohexene (55 and 55%), 3-methylcyclohexene (22 and 25%), and methylenecyclohexane (2 and 2%). The results obtained, together with those reported previously, support the conclusion that the pyrolysis may proceed, at least in part, through a free radical process. Nonstereospecificity in the direction of the pyrolysis may rule out a radical pair mechanism involving hydrogen participation
International audienceA detailed kinetic model consisting of 3883 free-radical reactions was develop...
Methyl formate (MF) is the smallest carboxylic ester and currently considered a promising alternativ...
2012-07-05Future internal combustion engine design will rely on accurate kinetic models of surrogate...
The pyrolysis of isopentyl and neopentyl P-toluenesulfonates in the liquid phase at 200°gave 2-methy...
The gas phase pyrolytic reaction of allyl formate (I), its α-methylated compound (II) and β- methyla...
Flash pyrolysis coupled to molecular beam extraction and single photon ionization time-of-flight mas...
The major dissociation reactions of the cyclohexene radical cation , 1, lead to cyclopentenyl ion by...
The formation of soot precursors during combustion of three positional isomers of methylcyclohexene ...
A study has been made of the pyrolysis of 1,5-hexadiene (diallyl) and of the reactions of the allyl ...
The role of methyl radicals in the networking of sp2 carbons has been explored through kinetic analy...
I. Two mechanisms have been proposed to account for the net single inversion of stereochemistry obse...
The radiolytic oxidation of anti-5-methylbicyclo(2.1.0)pentane gives the 1-methylcyclopentene radica...
As previous investigations on the thermal decomposition of cyclohexane give no consistent picture ab...
This research was undertaken to study the pyrolysis of toluene in the vapor phase. Many pyrolytic re...
The thermal decomposition of cyclohexanone (C6H10═O) has been studied in a set of flash-pyrolysis mi...
International audienceA detailed kinetic model consisting of 3883 free-radical reactions was develop...
Methyl formate (MF) is the smallest carboxylic ester and currently considered a promising alternativ...
2012-07-05Future internal combustion engine design will rely on accurate kinetic models of surrogate...
The pyrolysis of isopentyl and neopentyl P-toluenesulfonates in the liquid phase at 200°gave 2-methy...
The gas phase pyrolytic reaction of allyl formate (I), its α-methylated compound (II) and β- methyla...
Flash pyrolysis coupled to molecular beam extraction and single photon ionization time-of-flight mas...
The major dissociation reactions of the cyclohexene radical cation , 1, lead to cyclopentenyl ion by...
The formation of soot precursors during combustion of three positional isomers of methylcyclohexene ...
A study has been made of the pyrolysis of 1,5-hexadiene (diallyl) and of the reactions of the allyl ...
The role of methyl radicals in the networking of sp2 carbons has been explored through kinetic analy...
I. Two mechanisms have been proposed to account for the net single inversion of stereochemistry obse...
The radiolytic oxidation of anti-5-methylbicyclo(2.1.0)pentane gives the 1-methylcyclopentene radica...
As previous investigations on the thermal decomposition of cyclohexane give no consistent picture ab...
This research was undertaken to study the pyrolysis of toluene in the vapor phase. Many pyrolytic re...
The thermal decomposition of cyclohexanone (C6H10═O) has been studied in a set of flash-pyrolysis mi...
International audienceA detailed kinetic model consisting of 3883 free-radical reactions was develop...
Methyl formate (MF) is the smallest carboxylic ester and currently considered a promising alternativ...
2012-07-05Future internal combustion engine design will rely on accurate kinetic models of surrogate...