Structure of mu-oxo-bis{{2,2 '-[propane-1,3-diylbis (aminomethyl)]diphenolato}oxorhenium(V)}

[[abstract]]©2002 Springer - In the title compound, C34H40N4O7Re2, each of the two Re(V) atoms is hexacoordinated by two amine nitrogens, two phenol oxygens, and two axial oxygens. The compound is a binuclear complex with an O=Re-O-Re=O backbone and nearly octahedral coordination geometry at each Re atom. The Re=O bond distance is 1.720(14) Angstrom and the Re-O bridge bond distance is 1.938(12) Angstrom. The equatorial plane Re-O bond distances are 1.992(14) and 2.012(13) Angstrom, whereas the Re-N bond distances are 2.129(15) and 2.187(16) Angstrom.[[fileno]]2060213010006[[department]]醫環