Ordered mesoporous silicas with a channel structure of well-defined geometries and dimensions at nanometer scale are excellent candidates to host intercalation reactions. In recent years, our research group has shown that mesoporous silicas of the M41S class combined with metallocene complexes give rise to excellent supported catalysts for ethylene polymerisation. Due to the support characteristics, the reaction is allowed to occur in the channels and in this way hybrid organic-inorganic materials can be prepared within a large range of nanofiller concentration. These HDPE/MCM-41 nanocomposites exhibit an improved mechanical performance and an easier degradability due to the additional role of MCM-41 as a promoter for PE degradation
MCM-41 nanoparticles were used for preparing nanocomposites through the in situ polymerization of pr...
Meso/micro-porous solids, such as zeolites, are complex materials used in an impressive range of app...
Report on the discovery of a new group of ordered mesoporous M41S molecular sieves initiated the ext...
Ordered mesoporous silicas with a channel structure of well-defined geometries and dimensions at na...
Mesoporous MCM-41 exhibits a stable framework structure, well-defined nanopores and a large surface ...
New nanocomposites based on polyethylene have been prepared by in situ polymerization of ethylene in...
Polyethylene-based nanocomposites have been prepared by in situ polymerisation of ethylene with meso...
MCM-41 micro- and nanoparticles are prepared and functionalized with silane coupling agents. These p...
Mesoporous silicas exhibit stable three-dimensional structures, made of ordered channels with well-d...
A catalytic approach to synthesize microfine ultra-high molecular weight polyethylene (UHMWPE) parti...
Polyethylene-based nanocomposites have been prepared by in-situ polymerization of ethylene with meso...
An innovative approach, designated as supported activator (SA), allows preparation of high density p...
The synthesis of self-reinforced polyethylene-based materials prepared by in-situ polymerisation is ...
MCM-41 nanoparticles were used for preparing nanocomposites through the in situ polymerization of pr...
Despite the remarkable properties of ultra-high molecular weight polyethylene, itsapplication is lim...
MCM-41 nanoparticles were used for preparing nanocomposites through the in situ polymerization of pr...
Meso/micro-porous solids, such as zeolites, are complex materials used in an impressive range of app...
Report on the discovery of a new group of ordered mesoporous M41S molecular sieves initiated the ext...
Ordered mesoporous silicas with a channel structure of well-defined geometries and dimensions at na...
Mesoporous MCM-41 exhibits a stable framework structure, well-defined nanopores and a large surface ...
New nanocomposites based on polyethylene have been prepared by in situ polymerization of ethylene in...
Polyethylene-based nanocomposites have been prepared by in situ polymerisation of ethylene with meso...
MCM-41 micro- and nanoparticles are prepared and functionalized with silane coupling agents. These p...
Mesoporous silicas exhibit stable three-dimensional structures, made of ordered channels with well-d...
A catalytic approach to synthesize microfine ultra-high molecular weight polyethylene (UHMWPE) parti...
Polyethylene-based nanocomposites have been prepared by in-situ polymerization of ethylene with meso...
An innovative approach, designated as supported activator (SA), allows preparation of high density p...
The synthesis of self-reinforced polyethylene-based materials prepared by in-situ polymerisation is ...
MCM-41 nanoparticles were used for preparing nanocomposites through the in situ polymerization of pr...
Despite the remarkable properties of ultra-high molecular weight polyethylene, itsapplication is lim...
MCM-41 nanoparticles were used for preparing nanocomposites through the in situ polymerization of pr...
Meso/micro-porous solids, such as zeolites, are complex materials used in an impressive range of app...
Report on the discovery of a new group of ordered mesoporous M41S molecular sieves initiated the ext...