Synthesis and structure of a paramagnetic Mo3S4 incomplete cuboidal cluster with seven cluster skeletal electrons
- Petrov, Pavel A.
- Naumov, Dmitry Yu
- Llusar, Rosa
- Gómez García, Carlos J.
- Polo Ortiz, Victoriano
- Konchenko, Sergey N.
Publication date
August 2012
DOI Publisher
Royal Society of Chemistry (RSC) ISSN
1477-9226Abstract
The electron precise incomplete cuboidal complex [Mo3S4(dppe)3Br3]Br (1a) with 6 cluster skeletal electrons (CSE) and its halogen-mixed analogue [Mo3S4(dppe)3(Br,Cl)3](Br,Cl) (1b) can be smoothly reduced to the paramagnetic [Mo3S4(dppe)3X3] clusters (2a, X = Br; 2b, X = Cl/Br) with 7 CSE by treatment with liquid Ga
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