Allyl-allenyl zinc reagents undergo a rearrangement leading to allylic bis metallic species. A high regioselectivity is observed when these reagents are treated with a variety of electrophiles. The net result is an access to highly functionalized vinyl zinc reagents
Organozinc halides derived from Grignard reagents behave differently in their reaction with ethyl (±...
Allylindium dichloride is an effective reagent for carrying out photolytically initiated radical all...
Twenty-one allylstannanes have been prepared via a simple Wurtz-type coupling reaction of allyl brom...
Allylzinc (copper) reagents add to alkoxyallenes in a regioselective way, leading to ß-aikoxy vinyl ...
Abstract. The allylzincation of various vinyl metals can be performed at low temperatures. If the vi...
Pioneered by Wanklyn more than 150 years ago, organozincates have recently emerged as a versatile an...
Highly reactive zinc was prepared by the lithium naphthalenide reduction of zinc halides. This highl...
Thanks to iridium catalysis, arylzinc reagents undergo regioselective allylic substitution with very...
Allyl phenyl sulfides have proven to be extremely versatile and widely used reagents in organic chem...
7-Allylindolines are valuable synthons for designing biologically active molecular libraries. Lewis ...
Because of the concern for the environment and the search for the synthetic efficiency, the metal-me...
The methods described herein deal with the problem of precluding protection/deprotection and functio...
A new zinc-mediated coupling reaction of allyl and allyl-like bromides with Bu3SnCl (1) or Bu2SnCl2 ...
This thesis is focused on two important fields of palladium catalysis: the development of electrophi...
The insertion of zinc metal into primary alkyl chlorides, bromides, phosphates and sulfonates in a p...
Organozinc halides derived from Grignard reagents behave differently in their reaction with ethyl (±...
Allylindium dichloride is an effective reagent for carrying out photolytically initiated radical all...
Twenty-one allylstannanes have been prepared via a simple Wurtz-type coupling reaction of allyl brom...
Allylzinc (copper) reagents add to alkoxyallenes in a regioselective way, leading to ß-aikoxy vinyl ...
Abstract. The allylzincation of various vinyl metals can be performed at low temperatures. If the vi...
Pioneered by Wanklyn more than 150 years ago, organozincates have recently emerged as a versatile an...
Highly reactive zinc was prepared by the lithium naphthalenide reduction of zinc halides. This highl...
Thanks to iridium catalysis, arylzinc reagents undergo regioselective allylic substitution with very...
Allyl phenyl sulfides have proven to be extremely versatile and widely used reagents in organic chem...
7-Allylindolines are valuable synthons for designing biologically active molecular libraries. Lewis ...
Because of the concern for the environment and the search for the synthetic efficiency, the metal-me...
The methods described herein deal with the problem of precluding protection/deprotection and functio...
A new zinc-mediated coupling reaction of allyl and allyl-like bromides with Bu3SnCl (1) or Bu2SnCl2 ...
This thesis is focused on two important fields of palladium catalysis: the development of electrophi...
The insertion of zinc metal into primary alkyl chlorides, bromides, phosphates and sulfonates in a p...
Organozinc halides derived from Grignard reagents behave differently in their reaction with ethyl (±...
Allylindium dichloride is an effective reagent for carrying out photolytically initiated radical all...
Twenty-one allylstannanes have been prepared via a simple Wurtz-type coupling reaction of allyl brom...
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