a,ßethylenic ketones and a,ß, a',ß' diethylenic ketones with a stereodefined substitution pattern are easily prepared by coupling of alkenyl copper and cuprate reagents, directly obtained by carbocupration of alkynes, with acid chlorides and anhydrides in the presence of a catalytic amount of Pd° complex
Cooperative efforts: The catalytic coupling of the two organometallic intermediates is possible thro...
Based on the development of a novel and selective methodology of Zr-catalyzed carboalumination of al...
A Cu/Pd-catalyzed allylboration of alkynes with allyl carbonates and bis(pinacolato)diboron to aff...
The palladium (o) catalyzed coupling of acyl halides or anhydrides with alkenyl copper reagents furn...
A copper(I)-catalyzed enantioselective addition of enynes to ketones was developed. The method allo...
Stereoisomerically pure trisubstituted alpha,beta-unsaturated esters of general formula 7 have been ...
In this thesis, the paper is divided into 2 parts, each corresponding to 2 individual projects. We ...
Aryl and alkenylpalladium compounds generated by oxidative addition of a palladium(0) catalyst to th...
A new synthetic method, involving the copper(I) mediated intramolecular conjugate addition of alken...
Halohydrins, protected as ethers, acetals or chloro-magnesium alcoholates are sequentially transform...
A practical protocol for the hydroalkynylation of enones using Pd catalysis is reported. The reactio...
Reaction of organometallic reagents with allylic electrophiles is a synthetic methodology of potenti...
Acylketene O,S-acetals 1a-k undergo efficient and selective conjugate displacement of alkylthio grou...
Enantioenriched alcohols found in an array of bioactive natural products and pharmaceutical agents a...
Lithium diorganocuprates add across the triple bond of substituted and non-substituted acetylenic ac...
Cooperative efforts: The catalytic coupling of the two organometallic intermediates is possible thro...
Based on the development of a novel and selective methodology of Zr-catalyzed carboalumination of al...
A Cu/Pd-catalyzed allylboration of alkynes with allyl carbonates and bis(pinacolato)diboron to aff...
The palladium (o) catalyzed coupling of acyl halides or anhydrides with alkenyl copper reagents furn...
A copper(I)-catalyzed enantioselective addition of enynes to ketones was developed. The method allo...
Stereoisomerically pure trisubstituted alpha,beta-unsaturated esters of general formula 7 have been ...
In this thesis, the paper is divided into 2 parts, each corresponding to 2 individual projects. We ...
Aryl and alkenylpalladium compounds generated by oxidative addition of a palladium(0) catalyst to th...
A new synthetic method, involving the copper(I) mediated intramolecular conjugate addition of alken...
Halohydrins, protected as ethers, acetals or chloro-magnesium alcoholates are sequentially transform...
A practical protocol for the hydroalkynylation of enones using Pd catalysis is reported. The reactio...
Reaction of organometallic reagents with allylic electrophiles is a synthetic methodology of potenti...
Acylketene O,S-acetals 1a-k undergo efficient and selective conjugate displacement of alkylthio grou...
Enantioenriched alcohols found in an array of bioactive natural products and pharmaceutical agents a...
Lithium diorganocuprates add across the triple bond of substituted and non-substituted acetylenic ac...
Cooperative efforts: The catalytic coupling of the two organometallic intermediates is possible thro...
Based on the development of a novel and selective methodology of Zr-catalyzed carboalumination of al...
A Cu/Pd-catalyzed allylboration of alkynes with allyl carbonates and bis(pinacolato)diboron to aff...
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