Allylzinc (copper) reagents add to alkoxyallenes in a regioselective way, leading to ß-aikoxy vinyl metals. Allyl zinc derivatives react with a - lithoialkoxyallenes to generate regioselectively metallated ß-allene-enes
This PhD thesis describes work undertaken to effect asymmetric catalysis in hydroamination and hydro...
Secondary and tertiary alkylzinc bromides can be generated from the direct oxidative addition of Rie...
A unique method to affect intramolecular aminooxygenation and dioxygenation of allenols and allenyls...
Allyl-allenyl zinc reagents undergo a rearrangement leading to allylic bis metallic species. A high ...
A new gold-catalysed azidation reaction of allenes is presented as a new highly modular approach for...
Allyl phenyl sulfides have proven to be extremely versatile and widely used reagents in organic chem...
· Metal vinylidene generation · Reaction types · Vinylidenes as intermediates in catalytic reactions...
Chapters one and two focus on the effect of allenes as π-ligands on copper-promoted coupling reactio...
[[abstract]]Organometallics comprising an unsaturated hydrocarbyl group like an allyl, propargyl, al...
The copper catalyzed reaction of Grignard reagents with asymetric propargylic ethers leads to chiral...
Copper catalyzed 1,2-alkylesterification of 1,3-dienes with diacyl peroxides affords branched allyli...
Propargyl iodides are good precursors for allenylzincs via reaction with diethylzinc, even in nondeg...
Hydrozirconation of alkynes with the Schwartz reagent [Cp2Zr(H)Cl] provides vinyl zirconium species ...
DANS CE TRAVAIL, LA REACTIVITE D'ALLENYLZINCIQUES DANS DES REACTIONS DIASTEREOSELECTIVES A ETE ETUDI...
Phenethynyl cyclohexene oxide undergoes a reductive metallation by Buli and catalytic amount of CuI ...
This PhD thesis describes work undertaken to effect asymmetric catalysis in hydroamination and hydro...
Secondary and tertiary alkylzinc bromides can be generated from the direct oxidative addition of Rie...
A unique method to affect intramolecular aminooxygenation and dioxygenation of allenols and allenyls...
Allyl-allenyl zinc reagents undergo a rearrangement leading to allylic bis metallic species. A high ...
A new gold-catalysed azidation reaction of allenes is presented as a new highly modular approach for...
Allyl phenyl sulfides have proven to be extremely versatile and widely used reagents in organic chem...
· Metal vinylidene generation · Reaction types · Vinylidenes as intermediates in catalytic reactions...
Chapters one and two focus on the effect of allenes as π-ligands on copper-promoted coupling reactio...
[[abstract]]Organometallics comprising an unsaturated hydrocarbyl group like an allyl, propargyl, al...
The copper catalyzed reaction of Grignard reagents with asymetric propargylic ethers leads to chiral...
Copper catalyzed 1,2-alkylesterification of 1,3-dienes with diacyl peroxides affords branched allyli...
Propargyl iodides are good precursors for allenylzincs via reaction with diethylzinc, even in nondeg...
Hydrozirconation of alkynes with the Schwartz reagent [Cp2Zr(H)Cl] provides vinyl zirconium species ...
DANS CE TRAVAIL, LA REACTIVITE D'ALLENYLZINCIQUES DANS DES REACTIONS DIASTEREOSELECTIVES A ETE ETUDI...
Phenethynyl cyclohexene oxide undergoes a reductive metallation by Buli and catalytic amount of CuI ...
This PhD thesis describes work undertaken to effect asymmetric catalysis in hydroamination and hydro...
Secondary and tertiary alkylzinc bromides can be generated from the direct oxidative addition of Rie...
A unique method to affect intramolecular aminooxygenation and dioxygenation of allenols and allenyls...