Ba[6]Mg[11]F[34], a new compound of the pseudobinary BaF[2]–MgF[2] system, has been synthesized by solid state techniques from stoichiometric amounts of BaF[2] and MgF[2] and its crystal structure determined by single crystal X-ray diffraction (space group P1,a=7.5084(6), b=9.9192(8), c=10.0354(8) Å, α=81.563(2), β=72.402(2), γ=71.198(1)°, 3899 structure factors, 233 parameters, R(F[2]>2σ(F[2]))=0.018, wR(F[2] all) = 0.046). It is isotypic with the copper(II) analogue, Ba[6]Cu[11]F[34]. The main features of the structure are a network of [MgF[6]] octahedra and three different [BaF[x]] polyhedra with x=12, 11+1 and 13. Ba[6]Mg[11−x]Fe[x]F[34] and Ba[6]Mg[11−x]Mn[x]F[34] solid solutions were prepared and their composition determined by single...
A recent investigation of the (BaF2–MgF2) phase diagram produced several new compounds which are sui...
The title compound, hexabarium lead(II) dodecafluoride dichloride, is a solid solution in the system...
In orthorhombic Ba6Mg7F26, the Ba2+ ion can be partially replaced by Sr2+ to form a mixed, disordere...
Publisher Copyright: © 2021 The Authors. European Journal of Inorganic Chemistry published by Wiley-...
Two barium hexafluoridoosmates, Ba(OsF6)2 and BaOsF6, were synthesized and were characterized for th...
Barium calcium magnesium fluoride (Ba2(BaxCa1-x)Mg4F14, x=0.19-0.26) has been synthesized at 850 °C ...
Two barium hexafluoridoosmates, Ba(OsF6)2 and BaOsF6, were synthesized and were characterized for th...
Crystals of the title compound, with the idealized composition Ba2CaFeAl2F14, dibarium calcium iron(...
The solid solution series NaMgH3 amp; 8722;xFx x 0, 0.5, 1, 1.5, 2, 2.5, 3 was synthesized by so...
Convenient syntheses of mixed-metal Eu/Ba complexes starting from the elemental metals have been exp...
By solid state reaction, LiMgAlF6 and LiMgAlF6:Ln(3+) are synthetized with the ratio 120/100/110 of ...
International audienceThe compounds Ba3FeUS6 and Ba3AgUS6 have been synthesized by the reactions of ...
The BaMA(10)O(17) (M = Be, Mg, Ca, Zn, Cd, Mn, Co, Li) system has been synthesized by solid state me...
Crystals of ordered Ba6EuF12Cl2 were found to form during high temperature flux growth. The structur...
[Ba(C8F4O4)(C3H7NO)(C2H5OH)] or [Ba(tfBDC)(DMF)(EtOH)], where tfBDC2− = tetrafluoroterephthalate, DM...
A recent investigation of the (BaF2–MgF2) phase diagram produced several new compounds which are sui...
The title compound, hexabarium lead(II) dodecafluoride dichloride, is a solid solution in the system...
In orthorhombic Ba6Mg7F26, the Ba2+ ion can be partially replaced by Sr2+ to form a mixed, disordere...
Publisher Copyright: © 2021 The Authors. European Journal of Inorganic Chemistry published by Wiley-...
Two barium hexafluoridoosmates, Ba(OsF6)2 and BaOsF6, were synthesized and were characterized for th...
Barium calcium magnesium fluoride (Ba2(BaxCa1-x)Mg4F14, x=0.19-0.26) has been synthesized at 850 °C ...
Two barium hexafluoridoosmates, Ba(OsF6)2 and BaOsF6, were synthesized and were characterized for th...
Crystals of the title compound, with the idealized composition Ba2CaFeAl2F14, dibarium calcium iron(...
The solid solution series NaMgH3 amp; 8722;xFx x 0, 0.5, 1, 1.5, 2, 2.5, 3 was synthesized by so...
Convenient syntheses of mixed-metal Eu/Ba complexes starting from the elemental metals have been exp...
By solid state reaction, LiMgAlF6 and LiMgAlF6:Ln(3+) are synthetized with the ratio 120/100/110 of ...
International audienceThe compounds Ba3FeUS6 and Ba3AgUS6 have been synthesized by the reactions of ...
The BaMA(10)O(17) (M = Be, Mg, Ca, Zn, Cd, Mn, Co, Li) system has been synthesized by solid state me...
Crystals of ordered Ba6EuF12Cl2 were found to form during high temperature flux growth. The structur...
[Ba(C8F4O4)(C3H7NO)(C2H5OH)] or [Ba(tfBDC)(DMF)(EtOH)], where tfBDC2− = tetrafluoroterephthalate, DM...
A recent investigation of the (BaF2–MgF2) phase diagram produced several new compounds which are sui...
The title compound, hexabarium lead(II) dodecafluoride dichloride, is a solid solution in the system...
In orthorhombic Ba6Mg7F26, the Ba2+ ion can be partially replaced by Sr2+ to form a mixed, disordere...