Enantio- and Regioselective Conjugate Addition of Organometallic Reagents to Linear Polyconjugated Nitroolefins
- Tissot, Matthieu
- Alexakis, Alexandre
Publication date
January 2013
DOI Publisher
Wiley ISSN
0947-6539 Citation count (estimate)
16Abstract
The copper-catalysed conjugate addition of trialkylaluminium and dialkylzinc reagents to polyconjugated nitroolefins (nitrodiene and nitroenyne derivatives) is reported. A reversed Josiphos ligand L7 allows for the selective 1,4- or 1,6-addition with high enantioselectivities
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