Melanin is a natural pigment mainly responsible for theprotection of skin and eyes from UV damage. 5,6- dihydroxyindole-2 carboxylic acid (DHICA) is a key melanin building block.We have investigated the excited state dynamics of DHICA aswell as its derivatives and oligomeric units using ultrafastfluorescence spectroscopy. Time-resolved fluorescence experimentsrevealed single exponential decays of the excited state forall the molecules studied.The key observation was a sizedependent deactivation of the excited state.</p
International audienceExcited-state proton transfer has been hypothesized as a mechanism for UV ener...
Skin photoprotection is commonly believed to rely on the photochemistry of 5,6-dihydroxyindole (DHI)...
Skin photoprotection is commonly believed to rely on the photochemistry of 5,6-dihydroxyindole (DHI)...
Ultrafast time-resolved fluorescence spectroscopy has been used to investigate the excited-state dyn...
Ultrafast time-resolved fluorescence spectroscopy has been used to investigate the excited state d...
Ultrafast time-resolved fluorescence spectroscopy has been used to investigate the excited-state dyn...
Ultrafast time-resolved fluorescence spectroscopy has been used to investigate the excited-state dyn...
The UV-dissipative mechanisms of the eumelanin building block 5,6-dihydroxyindole-2-carboxylic acid ...
The UV-dissipative mechanisms of the eumelanin building block 5,6-dihydroxyindole-2-carboxylic acid ...
International audienceExcited-state proton transfer has been hypothesized as a mechanism for UV ener...
Skin photoprotection is commonly believed to rely on the photochemistry of 5,6-dihydroxyindole (DHI)...
Skin photoprotection is commonly believed to rely on the photochemistry of 5,6-dihydroxyindole (DHI)...
Ultrafast time-resolved fluorescence spectroscopy has been used to investigate the excited-state dyn...
Ultrafast time-resolved fluorescence spectroscopy has been used to investigate the excited state d...
Ultrafast time-resolved fluorescence spectroscopy has been used to investigate the excited-state dyn...
Ultrafast time-resolved fluorescence spectroscopy has been used to investigate the excited-state dyn...
The UV-dissipative mechanisms of the eumelanin building block 5,6-dihydroxyindole-2-carboxylic acid ...
The UV-dissipative mechanisms of the eumelanin building block 5,6-dihydroxyindole-2-carboxylic acid ...
International audienceExcited-state proton transfer has been hypothesized as a mechanism for UV ener...
Skin photoprotection is commonly believed to rely on the photochemistry of 5,6-dihydroxyindole (DHI)...
Skin photoprotection is commonly believed to rely on the photochemistry of 5,6-dihydroxyindole (DHI)...