Trigonal propeller-shaped [(Mn3MNa)-M-III-Na-II] complexes (M = Mn, Ca):structural and functional models for the dioxygen evolving centre of PSII

Nayak, Sanjit
Nayek, Hari Pada
Dehnen, Stefanie
Powell, Annie K.
Reedijk, Jan

Publication date

March 2011

DOI

Abstract

Two new polynuclear heterometallic cluster complexes with [MnIII3MIINa] (M = Mn, Ca) core were synthesized using two in situ formed Schiff bases. The compounds were structurally characterized by single crystal X-ray analysis. The compound with [MnIIICaIINa] appeared to catalyse water oxidation which was followed by using Clark electrode and online mass spectrometry.<br/

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Trigonal propeller-shaped [(Mn3MNa)-M-III-Na-II] complexes (M = Mn, Ca):structural and functional models for the dioxygen evolving centre of PSII

Abstract

Extracted data

Trigonal propeller-shaped [(Mn3MNa)-M-III-Na-II] complexes (M = Mn, Ca):structural and functional models for the dioxygen evolving centre of PSII

Abstract

Extracted data

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